{"title":"Arylation [Synthetic Reagents]","description":"\u003cp\u003e\u003cstrong\u003eArylation [Synthetic Reagents]\u003c\/strong\u003e — berisi garam iodonium diaril tidak simetris dengan berbagai gugus trifluorometil, metoksi, atau bromo, yang berpasangan dengan anion tosilat atau triflat sebagai elektrofil arilasi kuat dalam sintesis organik. Golongan ini termasuk reagen iod hipervalen yang aktif digunakan dalam kimia radikal dan katalisis fotoredoks.\u003c\/p\u003e\u003cp\u003eReagen iodonium ini dipakai peneliti sintesis organik untuk reaksi arilasi elektrofilik terhadap nukleofil oksigen, nitrogen, atau karbon, termasuk pada reaksi trifluorometilarilasi dan fungsionalisasi C-H terkatalisis logam maupun cahaya. Golongan ini juga populer sebagai mitra aril dalam reaksi fotoredoks dan katalisis radikal untuk membentuk ikatan karbon-karbon atau karbon-heteroatom baru.\u003c\/p\u003e\u003cp\u003eContoh produk dalam koleksi ini: \u003ca href=\"\/en\/products\/tci2510t362255277\"\u003eTCI T3622 1868173-15-2 [(4-Trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b557312236\"\u003eTCI B5573 1868173-47-0 4-Biphenylyl(2,4,6-trimethoxyphenyl)iodonium Trifluoromethanesulfonate\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510t344655075\"\u003eTCI T3446 1232133-62-8 [4-(Trifluoromethyl)phenyl](2,4,6-trimethylphenyl)iodonium Trifluoromethanesulfonate\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510d225322381\"\u003eTCI D2253 66003-76-7 Diphenyliodonium Trifluoromethanesulfonate\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510t344555073\"\u003eTCI T3445 1204518-08-0 [3-(Trifluoromethyl)phenyl](2,4,6-trimethylphenyl)iodonium Trifluoromethanesulfonate\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510d514525995\"\u003eTCI D5145 1868173-25-4 (3,5-Dichlorophenyl)(2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b527711886\"\u003eTCI B5277 1203709-76-5 (3-Bromophenyl)(mesityl)iodonium Trifluoromethanesulfonate\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510d588926880\"\u003eTCI D5889 1895006-01-5 Dimesityl(trifluoromethyl)sulfonium Trifluoromethanesulfonate\u003c\/a\u003e.\u003c\/p\u003e\u003cp\u003ePerhatikan jenis anion pendamping (triflat atau tosilat) yang memengaruhi reaktivitas dan kelarutan, pola substitusi pada kedua cincin aril, serta kestabilan senyawa terhadap kelembapan dan cahaya. Seluruh produk merupakan produk asli Tokyo Chemical Industry (TCI) Jepang, dengan kemurnian, kemasan, dan kondisi penyimpanan tercantum pada halaman masing-masing item.\u003c\/p\u003e\u003cp\u003eKategori lain yang sejajar di bawah Hypervalent Iodine Compounds [Synthetic Reagents], sering dipakai bersamaan dalam satu alur kerja laboratorium:\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-hypervalent-iodine-oxidation\"\u003eHypervalent Iodine [Oxidation]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-c-c-bond-formation-synthetic-reagents\"\u003eC-C Bond Formation [Synthetic Reagents]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-c-x-non-halogen-bond-formation-synthetic-reagents\"\u003eC-X(Non-Halogen) Bond Formation [Synthetic Reagents]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-protection-deprotection-derivatization\"\u003eProtection, Deprotection, Derivatization\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-acids-bases-synthetic-reagents\"\u003eAcids, Bases [Synthetic Reagents]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-chelation-complexation-compounds\"\u003eChelation\/Complexation Compounds\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003eKembali ke \u003ca href=\"\/en\/collections\/tci-l3-hypervalent-iodine-compounds-synthetic-reagents\"\u003eHypervalent Iodine Compounds [Synthetic Reagents]\u003c\/a\u003e. Untuk pengadaan volume besar, kemasan khusus, atau grade tertentu, hubungi tim AMI Scientific — distributor resmi TCI Japan di Indonesia — untuk pengecekan ketersediaan dan lead time langsung ke Jepang.\u003c\/p\u003e","products":[{"product_id":"tci2510p241348247","title":"TCI P2413 905718-46-9 Phenyl[3-(trifluoromethyl)phenyl]iodonium Trifluoromethanesulfonate","description":"\u003ch3\u003eDescription\u003c\/h3\u003e\n\u003cp\u003eTCI P2413 Phenyl[3-(trifluoromethyl)phenyl]iodonium Trifluoromethanesulfonate is a diaryliodonium salt. It is a hypervalent iodine compound that carries two different aryl groups, phenyl and 3-(trifluoromethyl)phenyl, with a triflate anion as its counterion. In organic synthesis laboratories it is used as an electrophilic arylating reagent, meaning it supplies an aryl group that can be transferred to a wide range of nucleophiles. Iodonium salts are also known as cationic photoinitiators and photoacid generators in polymer research and photoresist materials work.\u003c\/p\u003e\n\u003cp\u003eChemists choose diaryliodonium salts because they are relatively stable and are generally solids that are easy to handle, yet they transfer aryl groups very readily. The hypervalent iodine atom is an excellent leaving group, so arylation can proceed metal-free or with copper or palladium catalysts under fairly mild conditions. Because its two aryl groups are different, this unsymmetrical salt is useful for studying aryl-transfer selectivity, which depends on electronic factors and reaction conditions. The weakly coordinating triflate anion also improves reactivity and solubility in organic solvents.\u003c\/p\u003e\n\u003cp\u003eIn Indonesian laboratories, this reagent suits university organic chemistry research groups, pharmaceutical and medicinal chemistry teams, and materials science laboratories. Synthetic chemists can use it to build aryl–heteroatom and aryl–carbon bonds when developing new compounds or optimising reaction methods. Polymer and photoresist researchers can include it in studies of cationic photoinitiation and photoacid generation. As a TCI product, it gives research and teaching laboratories a recognised reagent source for reproducible synthetic work and method development.\u003c\/p\u003e\n\u003ch3\u003eLaboratory Applications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eElectrophilic arylation of nucleophiles: the iodonium centre transfers an aryl group to oxygen, nitrogen, sulfur or carbon nucleophiles, giving a practical route to arylated products.\u003c\/li\u003e\n\u003cli\u003eMetal-free arylation methods: the hypervalent iodine leaving group lets some arylations proceed without transition metals, which helps when metal residues in the product must be avoided.\u003c\/li\u003e\n\u003cli\u003eCopper- or palladium-catalysed coupling: the salt acts as a reactive aryl source in catalytic cycles under fairly mild conditions, which supports modern cross-coupling and C–H functionalisation research.\u003c\/li\u003e\n\u003cli\u003eAryl-transfer selectivity studies: the unsymmetrical phenyl and 3-(trifluoromethyl)phenyl groups let researchers study how electronic factors and reaction conditions decide which aryl group is transferred.\u003c\/li\u003e\n\u003cli\u003eCationic photoinitiation and photoacid generation research: iodonium salts are known photoinitiators and photoacid generators, so this compound fits exploratory work on polymer curing and photoresist materials.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eSpecifications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eBrand: TCI (product code P2413)\u003c\/li\u003e\n\u003cli\u003eCAS number: 905718-46-9\u003c\/li\u003e\n\u003cli\u003eCategory: Chemistry \u0026gt; Synthetic Reagents \u0026gt; Hypervalent Iodine Compounds\u003c\/li\u003e\n\u003cli\u003ePack sizes: as listed by TCI for product P2413; please confirm the available size when you order\u003c\/li\u003e\n\u003cli\u003ePhysical form: diaryliodonium salts are generally solids; see the TCI product documentation for details\u003c\/li\u003e\n\u003cli\u003eStorage: keep tightly closed in a cool, dry place, following the TCI label and Safety Data Sheet\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eHandling and Storage\u003c\/h3\u003e\n\u003cp\u003eStore this reagent in its original tightly sealed container, in a cool, dry, well-ventilated area away from direct light, heat and moisture. Iodonium salts are used as photoinitiators, so protecting the material from light helps preserve its quality. Keep it away from strong reducing agents and incompatible substances. Handle it in a fume hood and wear safety glasses, gloves and a laboratory coat. Avoid creating dust and avoid contact with skin and eyes. Always read the TCI Safety Data Sheet before use, and dispose of waste according to institutional and local chemical waste regulations.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48088120459482,"sku":"TCI2510P241348247","price":2626000.0,"currency_code":"IDR","in_stock":true},{"title":"5g","offer_id":48088120492250,"sku":"TCI2510P241348248","price":9161000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510P2413.jpg?v=1767136185"},{"product_id":"tci2510b525911863","title":"TCI B5259 139139-81-4 Bis(4-bromophenyl)iodonium Trifluoromethanesulfonate","description":"\u003cp\u003e\u003cstrong\u003eBis(4-bromophenyl)iodonium Trifluoromethanesulfonate\u003c\/strong\u003e (CAS 139139-81-4) is a high-quality chemical from TCI, supplied as \u003cstrong\u003eHPLC Grade\u003c\/strong\u003e.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eApplication:\u003c\/strong\u003e Synthesis reagent for a wide range of organic chemistry transformations in laboratory and industrial settings.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eSpecifications:\u003c\/strong\u003e\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eMolecular formula: C13H8Br2F3IO3S\u003c\/li\u003e\n\u003cli\u003eCAS number: 139139-81-4\u003c\/li\u003e\n\u003cli\u003ePurity: \u0026gt;98.0%(HPLC)(T)\u003c\/li\u003e\n\u003cli\u003eTCI product code: B5259\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003e\u003cstrong\u003eSynonyms:\u003c\/strong\u003e Bis(4-bromophenyl)iodonium Triflate\u003c\/p\u003e\u003cp\u003eAvailable from \u003cstrong\u003eAMI Scientific\u003c\/strong\u003e, the authorised TCI distributor in Indonesia. \u003cstrong\u003eContact us for pricing and stock availability\u003c\/strong\u003e — we ship throughout Indonesia.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48085862252762,"sku":"TCI2510B525911863","price":2323000.0,"currency_code":"IDR","in_stock":true},{"title":"5g","offer_id":48085862285530,"sku":"TCI2510B525911864","price":8227000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510B5259_c2d86f4f-c243-4130-a3a0-d61b81e60eff.jpg?v=1767856115"},{"product_id":"tci2510b527711886","title":"TCI B5277 1203709-76-5 (3-Bromophenyl)(mesityl)iodonium Trifluoromethanesulfonate","description":"\u003cp\u003e\u003cstrong\u003e(3-Bromophenyl)(mesityl)iodonium Trifluoromethanesulfonate\u003c\/strong\u003e (CAS 1203709-76-5) is a high-quality chemical from TCI, supplied as \u003cstrong\u003eReagent Grade \/ for Synthesis\u003c\/strong\u003e.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eApplication:\u003c\/strong\u003e Synthesis reagent for a wide range of organic chemistry transformations in laboratory and industrial settings.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eSpecifications:\u003c\/strong\u003e\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eMolecular formula: C16H15BrF3IO3S\u003c\/li\u003e\n\u003cli\u003eCAS number: 1203709-76-5\u003c\/li\u003e\n\u003cli\u003ePurity: \u0026gt;98.0%(T)\u003c\/li\u003e\n\u003cli\u003eTCI product code: B5277\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003e\u003cstrong\u003eSynonyms:\u003c\/strong\u003e (3-Bromophenyl)(mesityl)iodonium Triflate\u003c\/p\u003e\u003cp\u003eAvailable from \u003cstrong\u003eAMI Scientific\u003c\/strong\u003e, the authorised TCI distributor in Indonesia. \u003cstrong\u003eContact us for pricing and stock availability\u003c\/strong\u003e — we ship throughout Indonesia.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48085864055002,"sku":"TCI2510B527711886","price":3131000.0,"currency_code":"IDR","in_stock":true},{"title":"5g","offer_id":48085864087770,"sku":"TCI2510B527711887","price":10727000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510B5277_5cb9a322-a18d-4379-b714-dc7b3a0fe7dc.jpg?v=1767861399"}],"url":"https:\/\/amiscientific.com\/en\/collections\/tci-l4-arylation-synthetic-reagents.oembed","provider":"AMI Scientific","version":"1.0","type":"link"}