{"title":"Hypervalent Iodine [Oxidation]","description":"\u003cp\u003e\u003cstrong\u003eHypervalent Iodine [Oxidation]\u003c\/strong\u003e — menghimpun reagen iodin hipervalen seperti turunan benziodoksol dan iodobenzena terhalogenasi yang berperan sebagai oksidator elektrofilik kuat dalam sintesis organik. Kelompok senyawa ini banyak dipakai untuk menggantikan oksidator berbasis logam berat pada berbagai transformasi gugus fungsi.\u003c\/p\u003e\u003cp\u003eHypervalent Iodine [Oxidation] dipakai peneliti sintesis organik untuk oksidasi alkohol menjadi aldehida atau keton, misalnya melalui reagen tipe IBX dan turunannya. Senyawa seperti [Bis(trifluoroacetoxy)iodo]pentafluorobenzene dan turunan benziodoksol lain juga dimanfaatkan pada reaksi aminasi, oksidasi C–H, serta pembentukan ikatan karbon-heteroatom dalam alur sintesis molekul kompleks di laboratorium akademik maupun industri farmasi.\u003c\/p\u003e\u003cp\u003eContoh produk dalam koleksi ini: \u003ca href=\"\/en\/products\/tci2510i079136055\"\u003eTCI I0791 61717-82-6 2-Iodoxybenzoic Acid (stabilized with Benzoic Acid + Isophthalic Acid)\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510d204522082\"\u003eTCI D2045 87413-09-0 Dess-Martin Periodinane\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b540512042\"\u003eTCI B5405 57357-20-7 [Bis(tert-butylcarbonyloxy)iodo]benzene\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510d447725077\"\u003eTCI D4477 87413-09-0 Dess-Martin Periodinane (8-12% in Dichloromethane)\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b25398202\"\u003eTCI B2539 15656-28-7 Bis(pyridine)iodonium Tetrafluoroborate\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510i007335032\"\u003eTCI I0073 304-91-6 2-Iodosobenzoic Acid\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b16166968\"\u003eTCI B1616 14353-88-9 [Bis(trifluoroacetoxy)iodo]pentafluorobenzene\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510i033035396\"\u003eTCI I0330 3240-34-4 Iodobenzene Diacetate\u003c\/a\u003e.\u003c\/p\u003e\u003cp\u003ePemilihan bergantung pada kestabilan reagen saat penyimpanan, misalnya bentuk yang distabilkan dengan asam benzoat dan isoftalat, serta tingkat kemurnian dan bentuk kristal yang memengaruhi reaktivitas dalam reaksi oksidasi. Seluruh produk merupakan produk asli Tokyo Chemical Industry (TCI) Jepang, dengan kemurnian, kemasan, dan kondisi penyimpanan tercantum pada halaman masing-masing item.\u003c\/p\u003e\u003cp\u003eKategori lain yang sejajar di bawah Hypervalent Iodine Compounds [Synthetic Reagents], sering dipakai bersamaan dalam satu alur kerja laboratorium:\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-arylation-synthetic-reagents\"\u003eArylation [Synthetic Reagents]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-c-c-bond-formation-synthetic-reagents\"\u003eC-C Bond Formation [Synthetic Reagents]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-c-x-non-halogen-bond-formation-synthetic-reagents\"\u003eC-X(Non-Halogen) Bond Formation [Synthetic Reagents]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-protection-deprotection-derivatization\"\u003eProtection, Deprotection, Derivatization\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-acids-bases-synthetic-reagents\"\u003eAcids, Bases [Synthetic Reagents]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l3-chelation-complexation-compounds\"\u003eChelation\/Complexation Compounds\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003eKembali ke \u003ca href=\"\/en\/collections\/tci-l3-hypervalent-iodine-compounds-synthetic-reagents\"\u003eHypervalent Iodine Compounds [Synthetic Reagents]\u003c\/a\u003e. Untuk pengadaan volume besar, kemasan khusus, atau grade tertentu, hubungi tim AMI Scientific — distributor resmi TCI Japan di Indonesia — untuk pengecekan ketersediaan dan lead time langsung ke Jepang.\u003c\/p\u003e","products":[{"product_id":"tci2510d204522082","title":"TCI D2045 87413-09-0 Dess-Martin Periodinane","description":"\u003ch3\u003eDescription\u003c\/h3\u003e\n\u003cp\u003eTCI D2045 Dess-Martin Periodinane is an oxidizing reagent belonging to the hypervalent iodine class of compounds, and it is one of the most widely recognized oxidants in synthetic organic chemistry. Its primary function is to oxidize primary alcohols to aldehydes and secondary alcohols to ketones cleanly, rapidly, and under very mild conditions. The reagent has become a standard choice in many laboratories because it stops the oxidation precisely at the aldehyde stage without allowing the reaction to proceed on to the carboxylic acid — an outcome that is difficult to achieve with many other oxidants, particularly on complex, densely functionalized molecules.\u003c\/p\u003e\n\u003cp\u003eThe advantages that lead chemists to select this reagent lie in its selectivity and the gentleness of its reaction conditions. Oxidations generally proceed at room temperature in dichloromethane, require no strongly acidic medium, and typically leave double bonds, protecting groups, and stereogenic centers prone to epimerization untouched. The reagent also contains no heavy metals such as chromium, so waste handling is more straightforward and the risk of metal toxicity is reduced. Its solid form makes weighing convenient and allows the number of equivalents to be controlled accurately during reaction setup.\u003c\/p\u003e\n\u003cp\u003eIn Indonesian laboratories, Dess-Martin Periodinane is typically used in synthetic organic chemistry research groups at universities and in research institutes where alcohol-to-carbonyl conversions must be carried out on valuable or sensitive intermediates. It suits work on multi-step syntheses of natural products and pharmaceutical intermediates, where a clean, mild, and selective oxidation step is needed. As an important note, this reagent belongs to the category of materials that must be handled with appropriate care.\u003c\/p\u003e\n\u003ch3\u003eLaboratory Applications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eOxidation of primary alcohols to aldehydes — the reaction stops cleanly at the aldehyde stage without over-oxidation to the carboxylic acid, which is difficult with many conventional oxidants.\u003c\/li\u003e\n\u003cli\u003eOxidation of secondary alcohols to ketones — proceeds rapidly at room temperature in dichloromethane, giving clean conversion without requiring a strongly acidic reaction medium.\u003c\/li\u003e\n\u003cli\u003eMulti-step synthesis of complex, densely functionalized molecules — the reagent's high selectivity allows a single hydroxyl group to be oxidized while other functional groups remain intact.\u003c\/li\u003e\n\u003cli\u003eSynthesis involving epimerization-sensitive substrates — the mild, non-acidic conditions generally leave stereogenic centers unaffected, preserving the stereochemical integrity of valuable intermediates.\u003c\/li\u003e\n\u003cli\u003eChromium-free oxidation workflows — because the reagent contains no heavy metals, laboratories can avoid metal toxicity risks and simplify the treatment of their chemical waste streams.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eSpecifications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eBrand: TCI\u003c\/li\u003e\n\u003cli\u003eCAS Number: 87413-09-0\u003c\/li\u003e\n\u003cli\u003eCategory: Chemistry \u0026gt; Synthetic Reagents \u0026gt; Hypervalent Iodine Compounds [Synthetic Reagents]\u003c\/li\u003e\n\u003cli\u003eProduct Code: D2045\u003c\/li\u003e\n\u003cli\u003ePhysical Form: Solid, which facilitates accurate weighing and control of reaction equivalents\u003c\/li\u003e\n\u003cli\u003eStorage: Store according to the conditions stated on the manufacturer's label and safety data sheet\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eHandling and Storage\u003c\/h3\u003e\n\u003cp\u003eStore the reagent in its original tightly closed container in a cool, dry, and well-ventilated area, following the storage conditions given on the manufacturer's label and safety data sheet. Keep containers protected from moisture, heat, and sources of ignition, and keep them separated from incompatible materials, particularly reducing agents and readily oxidizable organic substances. This is a material that must be handled with appropriate care: weigh and transfer it in a fume hood, wear gloves, safety glasses, and a laboratory coat, avoid mechanical shock and friction, and dispose of residues and reaction waste through the laboratory's established chemical waste procedures. Always consult the current safety data sheet before use.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48086490448090,"sku":"TCI2510D204522082","price":1659000.0,"currency_code":"IDR","in_stock":true},{"title":"5g","offer_id":48086490480858,"sku":"TCI2510D204522083","price":4919000.0,"currency_code":"IDR","in_stock":true},{"title":"25g","offer_id":48086490513626,"sku":"TCI2510D204522084","price":15796000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510D2045.jpg?v=1767104100"},{"product_id":"tci2510d447725077","title":"TCI D4477 87413-09-0 Dess-Martin Periodinane (8-12% in Dichloromethane)","description":"\u003ch3\u003eDescription\u003c\/h3\u003e\n\u003cp\u003eDess-Martin Periodinane is a widely used chemical reagent in organic synthesis, serving as an effective oxidizing agent. It is particularly valued for its ability to selectively oxidize a variety of organic compounds, including alcohols, phenols, and aromatic compounds, into more complex structures. This reagent plays a crucial role in laboratory settings where precise and controlled oxidation reactions are required. Its versatility makes it a key component in the development of new chemical compounds and the modification of existing ones.\u003c\/p\u003e\n\u003cp\u003eThe properties of Dess-Martin Periodinane that make it a preferred choice include its stability under specific conditions and its high reactivity towards a wide range of substrates. It is non-corrosive and relatively safe when handled properly, which enhances its usability in laboratory environments. These characteristics contribute to its reliability and efficiency in chemical reactions, making it a go-to reagent for chemists seeking consistent results. Its ease of use and effectiveness further support its popularity in both academic and industrial research settings.\u003c\/p\u003e\n\u003cp\u003eIn Indonesian laboratories, Dess-Martin Periodinane is commonly utilized in organic chemistry research conducted by universities and research institutions. Its application is relevant in the development of new compounds and the refinement of existing chemical structures. The reagent is particularly useful in projects that require oxidation reactions with high stability and efficiency. Its presence in Indonesian laboratories underscores its importance in advancing chemical research and innovation.\u003c\/p\u003e\n\u003ch3\u003eLaboratory Applications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eOrganic synthesis reactions benefit from Dess-Martin Periodinane due to its selective oxidation capabilities, enabling the formation of complex organic molecules with high yield.\u003c\/li\u003e\n\u003cli\u003eOxidation of alcohols to ketones or carboxylic acids is efficiently achieved using this reagent, offering a reliable alternative to other oxidizing agents.\u003c\/li\u003e\n\u003cli\u003eAromatic compound functionalization is enhanced by the reagent’s ability to selectively oxidize specific functional groups without affecting other parts of the molecule.\u003c\/li\u003e\n\u003cli\u003ePharmaceutical compound development leverages the reagent’s precision in modifying molecular structures, supporting the creation of new drug candidates.\u003c\/li\u003e\n\u003cli\u003eAcademic research in chemistry utilizes Dess-Martin Periodinane for teaching and experimental purposes, providing students with hands-on experience in oxidation reactions.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eSpecifications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eBrand: TCI\u003c\/li\u003e\n\u003cli\u003eCAS number: 87413-09-0\u003c\/li\u003e\n\u003cli\u003eCategory: Chemistry \u0026gt; Synthetic Reagents \u0026gt; Hypervalent Iodine Compounds\u003c\/li\u003e\n\u003cli\u003ePack sizes: Available in various sizes as per supplier specifications\u003c\/li\u003e\n\u003cli\u003ePhysical form: Solid or solution in dichloromethane\u003c\/li\u003e\n\u003cli\u003eStorage note: Store in a cool, dry place away from light and incompatible materials\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eHandling and Storage\u003c\/h3\u003e\n\u003cp\u003eDess-Martin Periodinane should be stored in a cool, dry environment, away from direct sunlight and sources of heat. It is recommended to keep the reagent in tightly sealed containers to prevent exposure to moisture and air. Due to its chemical nature, it should be stored separately from strong bases, reducing agents, and other reactive substances. Proper ventilation is essential when handling the reagent to minimize inhalation risks. Laboratory personnel should wear appropriate personal protective equipment, such as gloves and safety goggles, to ensure safe handling. Regular monitoring of storage conditions is advised to maintain the reagent’s stability and effectiveness.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"25mL","offer_id":48086693511386,"sku":"TCI2510D447725077","price":2306000.0,"currency_code":"IDR","in_stock":true},{"title":"250mL","offer_id":48086693544154,"sku":"TCI2510D447725078","price":13548000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510D4477.jpg?v=1767107618"},{"product_id":"tci2510i007335032","title":"TCI I0073 304-91-6 2-Iodosobenzoic Acid","description":"\u003cp\u003e\u003cstrong\u003e2-Iodosobenzoic Acid\u003c\/strong\u003e (CAS 304-91-6) is a high-quality chemical from TCI, supplied as \u003cstrong\u003eReagent Grade \/ for Synthesis\u003c\/strong\u003e.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eApplication:\u003c\/strong\u003e Synthesis reagent for a wide range of organic chemistry transformations in laboratory and industrial settings.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eSpecifications:\u003c\/strong\u003e\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eMolecular formula: C7H5IO3\u003c\/li\u003e\n\u003cli\u003eCAS number: 304-91-6\u003c\/li\u003e\n\u003cli\u003ePurity: \u0026gt;98.0%(T)\u003c\/li\u003e\n\u003cli\u003eTCI product code: I0073\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003e\u003cstrong\u003eSynonyms:\u003c\/strong\u003e 1-Hydroxy-1,2-benziodoxol-3(1H)-one; 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