{"title":"Organosilicon Compounds (Other) [Organosilicon]","description":"\u003cp\u003e\u003cstrong\u003eOrganosilicon Compounds (Other) [Organosilicon]\u003c\/strong\u003e — menghimpun senyawa organosilikon di luar kelompok silan klorida atau alkoksisilan umum, termasuk turunan sililoksi, silazana, dan aril silan yang mengandung ikatan Si-C maupun Si-N\/Si-O. Berperan sebagai gugus pelindung, pereaksi sililasi, atau blok bangun untuk modifikasi molekul dalam sintesis organik.\u003c\/p\u003e\u003cp\u003eOrganosilicon Compounds (Other) banyak dipakai untuk melindungi gugus hidroksil atau amina selama sintesis multi-tahap, misalnya melalui gugus tert-butildimetilsilil (TBS) seperti pada B5555 dan B5851, sehingga reaksi berikutnya dapat berlangsung selektif. Turunan trimetilsilil eter dan silazana juga dimanfaatkan dalam kimia polimer dan modifikasi material untuk memfungsionalisasi permukaan atau sebagai monomer tersilil.\u003c\/p\u003e\u003cp\u003eContoh produk dalam koleksi ini: \u003ca href=\"\/en\/products\/tci2510u018256389\"\u003eTCI U0182 2762957-87-7 N-Sulfinyltriisopropylsilylamine\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b555512213\"\u003eTCI B5555 73842-99-6 3-[[tert-Butyl(dimethyl)silyl]oxy]-1-propanol\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510t403455765\"\u003eTCI T4034 27804-64-4 N,N,N',N'-Tetraethylsilanediamine\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b585112608\"\u003eTCI B5851 102229-10-7 2-[[tert-Butyl(dimethyl)silyl]oxy]ethanol\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510t391955634\"\u003eTCI T3919 1009-43-4 Trimethyl(4-vinylphenyl)silane (stabilized with TBC)\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b587412637\"\u003eTCI B5874 101711-55-1 2-[[tert-Butyl(dimethyl)silyl]oxy]ethylamine\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510t374955436\"\u003eTCI T3749 1174-72-7 Tetraphenyl Orthosilicate\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b587612640\"\u003eTCI B5876 14642-79-6 Benzyloxytrimethylsilane\u003c\/a\u003e.\u003c\/p\u003e\u003cp\u003ePerhatikan jenis gugus pelindung silil (TMS, TBS, dan sejenisnya), kemurnian, serta kepekaan terhadap kelembapan sehingga kemasan kedap udara dan pelarut anhidrat perlu disiapkan sesuai reaksi yang dituju. Seluruh produk merupakan produk asli Tokyo Chemical Industry (TCI) Jepang, dengan kemurnian, kemasan, dan kondisi penyimpanan tercantum pada halaman masing-masing item.\u003c\/p\u003e\u003cp\u003eKategori lain yang sejajar di bawah Organosilicon [Organometallic Reagents], sering dipakai bersamaan dalam satu alur kerja laboratorium:\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-trialkoxysilanes-organosilicon\"\u003eTrialkoxysilanes [Organosilicon]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-hydrosilanes-organosilicon\"\u003eHydrosilanes [Organosilicon]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-siloxanes-organosilicon\"\u003eSiloxanes [Organosilicon]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-ethynylsilanes-organosilicon\"\u003eEthynylsilanes [Organosilicon]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-clorosilanes-organosilicon\"\u003eClorosilanes [Organosilicon]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-vinylsilanes-organosilicon\"\u003eVinylsilanes [Organosilicon]\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003eKembali ke \u003ca href=\"\/en\/collections\/tci-l3-organosilicon-organometallic-reagents\"\u003eOrganosilicon [Organometallic Reagents]\u003c\/a\u003e. Untuk pengadaan volume besar, kemasan khusus, atau grade tertentu, hubungi tim AMI Scientific — distributor resmi TCI Japan di Indonesia — untuk pengecekan ketersediaan dan lead time langsung ke Jepang.\u003c\/p\u003e","products":[{"product_id":"tci2510d424324786","title":"TCI D4243 321903-29-1 1,1-Dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole","description":"\u003ch3\u003eDescription\u003c\/h3\u003e\n\u003cp\u003eTCI D4243 1,1-Dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole (CAS 321903-29-1) is a cyclic organosilicon reagent that combines a silicon atom, an oxygen atom, and a benzene framework within a single five-membered ring. Among synthetic chemists, this compound is known as an aryl donor that plays a role in palladium-catalyzed cross-coupling reactions, particularly in the Hiyama–Denmark approach. The cyclic oxasilole form acts as a protected form of a silanol, so the reagent can be handled more conveniently while remaining easy to activate at the moment of reaction in order to transfer the aryl group to its electrophilic partner.\u003c\/p\u003e\n\u003cp\u003eThe principal characteristic that leads chemists to select this reagent is the controllable reactivity of silicon. In contrast to highly reactive organometallic reagents, organosilicon compounds are generally more stable, more tolerant of a wide range of functional groups, and generate silicon-based by-products that are relatively innocuous and straightforward to separate. The strained oxasilole ring allows activation to proceed efficiently when the compound is exposed to a suitable base or activator, so transfer of the aryl group takes place with good results. The combination of storage stability and ready activation on demand is what makes this reagent a practical choice for bench-scale synthesis.\u003c\/p\u003e\n\u003cp\u003eIn Indonesian laboratories, this reagent is typically encountered in university and institutional research groups working on organic synthesis and methodology development, as well as in research and development units that prepare aryl-substituted intermediates. It is generally used in small quantities within schlenk-line or inert-atmosphere setups where palladium catalysis is already established, and it suits groups that prefer a milder alternative to more aggressive organometallic aryl donors while maintaining reproducible coupling outcomes across a variety of substrates.\u003c\/p\u003e\n\u003ch3\u003eLaboratory Applications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eHiyama–Denmark cross-coupling: the cyclic oxasilole serves as a masked silanol that is activated in situ, transferring its aryl group to an electrophilic partner under palladium catalysis with good efficiency.\u003c\/li\u003e\n\u003cli\u003eBiaryl scaffold construction: the reagent supplies an aryl unit for building biaryl linkages, offering milder conditions than highly reactive organometallic donors while remaining compatible with sensitive functional groups.\u003c\/li\u003e\n\u003cli\u003eSynthetic methodology development: research groups use this oxasilole to study silicon activation, base and activator selection, and catalyst systems that govern aryl transfer efficiency in coupling reactions.\u003c\/li\u003e\n\u003cli\u003eFunctionalized intermediate preparation: because organosilicon reagents tolerate a broad range of functional groups, this compound suits couplings on substrates that would not survive more aggressive aryl-donor chemistry.\u003c\/li\u003e\n\u003cli\u003eCleaner work-up coupling routes: the silicon-based by-products generated during the reaction are relatively innocuous and easy to separate, simplifying purification compared with several alternative cross-coupling reagent classes.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eSpecifications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eBrand: TCI\u003c\/li\u003e\n\u003cli\u003eCAS number: 321903-29-1\u003c\/li\u003e\n\u003cli\u003eCategory: Chemistry \u0026gt; Organometallic Reagents \u0026gt; Organosilicon [Organometallic Reagents]\u003c\/li\u003e\n\u003cli\u003eProduct code: D4243\u003c\/li\u003e\n\u003cli\u003ePack sizes: available in the pack sizes offered by TCI for this catalogue item; please confirm the required size when ordering.\u003c\/li\u003e\n\u003cli\u003eStorage: store as an organosilicon reagent, in a tightly closed original container kept cool and dry.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eHandling and Storage\u003c\/h3\u003e\n\u003cp\u003eKeep this reagent in its original tightly closed container, stored in a cool, dry, and well-ventilated location away from moisture, heat, direct sunlight, and ignition sources. Because organosilicon compounds of this type can be sensitive to moisture, containers should be resealed promptly after use, and transfers are best carried out under an inert atmosphere using dry glassware and dry solvents. Handle the material in a fume hood with appropriate personal protective equipment, including safety goggles, chemical-resistant gloves, and a laboratory coat. Store separately from strong oxidizing agents and incompatible chemicals, and always consult the manufacturer's safety data sheet before use and before disposal of residues.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48086680862938,"sku":"TCI2510D424324786","price":3654000.0,"currency_code":"IDR","in_stock":true},{"title":"5g","offer_id":48086680895706,"sku":"TCI2510D424324787","price":14306000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510D4243.jpg?v=1769141971"},{"product_id":"tci2510h141334260","title":"TCI H1413 752-28-3 1,1,2,3,4,5-Hexaphenylsilole","description":"\u003ch3\u003eDescription\u003c\/h3\u003e\n\u003cp\u003e1,1,2,3,4,5-Hexaphenylsilole is an organosilicon compound built around a silole ring, a five-membered heterocycle containing a silicon atom, in which every available position carries a phenyl substituent. The material is widely recognised as a reference molecule in the study of aggregation-induced emission, a phenomenon in which a molecule emits light far more strongly in the aggregated or solid state than it does in dilute solution. In the laboratory, this compound serves as an important benchmark for researchers developing luminescent materials, fluorescent probes, and organic electronic devices.\u003c\/p\u003e\n\u003cp\u003eThe property that makes this compound distinctive originates in the propeller-like geometry of the phenyl groups arranged around the silole core. In solution, free rotation of these groups dissipates excitation energy through non-radiative pathways, so luminescence remains weak. When the molecules aggregate or are held within a solid matrix, that rotation is restricted and the radiative pathway becomes dominant, so emission intensifies. In addition, the silole ring possesses a comparatively low-lying unoccupied orbital level arising from interaction between the silicon orbitals and the diene system, which makes it attractive as an electron-transporting material in device research.\u003c\/p\u003e\n\u003cp\u003eIn Indonesian laboratories, this reagent is typically used within university and institutional research groups working on photophysics, materials chemistry, and organic electronics. It is commonly employed as a positive control or comparison standard when new aggregation-induced emission systems are being characterised, and it supports teaching and thesis work in advanced chemistry programmes. Research centres developing sensing platforms and thin-film devices also keep this compound on hand as a well-documented point of reference.\u003c\/p\u003e\n\u003ch3\u003eLaboratory Applications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eAggregation-induced emission studies: serves as the classic reference molecule against which the emission behaviour of newly synthesised luminogens can be compared under identical measurement conditions.\u003c\/li\u003e\n\u003cli\u003eFluorescent probe development: its strong solid-state and aggregate emission makes it a useful model for designing probes that must report signal in condensed or bound environments.\u003c\/li\u003e\n\u003cli\u003eOrganic electronic device research: the low-lying unoccupied orbital level of the silole ring supports its evaluation as an electron-transporting component in experimental device architectures.\u003c\/li\u003e\n\u003cli\u003ePhotophysical characterisation and method validation: provides a well-documented emission response for calibrating and verifying fluorescence spectrometers and solid-state measurement setups in the laboratory.\u003c\/li\u003e\n\u003cli\u003eOrganosilicon and heterocycle chemistry teaching: offers a concrete example of how silicon incorporation into a five-membered ring alters electronic structure and optical behaviour for advanced coursework.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eSpecifications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eBrand: TCI\u003c\/li\u003e\n\u003cli\u003eCAS number: 752-28-3\u003c\/li\u003e\n\u003cli\u003eCatalogue code: H1413\u003c\/li\u003e\n\u003cli\u003eCategory: Chemistry \u0026gt; Organometallic Reagents \u0026gt; Organosilicon [Organometallic Reagents]\u003c\/li\u003e\n\u003cli\u003ePack sizes: available in standard research-scale catalogue pack sizes\u003c\/li\u003e\n\u003cli\u003eStorage: keep in a cool, dry place in the original tightly closed container\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eHandling and Storage\u003c\/h3\u003e\n\u003cp\u003eStore the container in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and strong oxidising agents. Keep the material in its original tightly closed container, or in a clean amber glass vessel, to limit exposure to moisture and light. Handle the compound in a fume hood using a laboratory coat, chemical-resistant gloves, and safety goggles, and avoid generating dust when weighing. Return the container promptly after use, label any secondary containers clearly, and dispose of residues and contaminated materials through the laboratory's established chemical waste procedures. Always consult the manufacturer's safety data sheet before first use.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48087287365850,"sku":"TCI2510H141334260","price":3486000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510H1413.jpg?v=1768205566"},{"product_id":"tci2510o049144896","title":"TCI O0491 69655-76-1 Octavinyloctasilasesquioxane","description":"\u003cp\u003e\u003cstrong\u003eOctavinyloctasilasesquioxane\u003c\/strong\u003e (CAS 69655-76-1) is a high-quality chemical from TCI, supplied as \u003cstrong\u003eReagent Grade\u003c\/strong\u003e.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eApplication:\u003c\/strong\u003e Synthesis reagent for a wide range of organic chemistry transformations in laboratory and industrial settings.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eSpecifications:\u003c\/strong\u003e\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eMolecular formula: C16H24O12Si8\u003c\/li\u003e\n\u003cli\u003eCAS number: 69655-76-1\u003c\/li\u003e\n\u003cli\u003eTCI product code: O0491\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003e\u003cstrong\u003eSynonyms:\u003c\/strong\u003e 1,3,5,7,9,11,13,15-Octavinylpentacyclo[9.5.1.1(3,9).1(5,15).1(7,13)]octasiloxane\u003c\/p\u003e\u003cp\u003eAvailable from \u003cstrong\u003eAMI Scientific\u003c\/strong\u003e, the authorised TCI distributor in Indonesia. \u003cstrong\u003eContact us for pricing and stock availability\u003c\/strong\u003e — we ship throughout Indonesia.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48087913464026,"sku":"TCI2510O049144896","price":1969000.0,"currency_code":"IDR","in_stock":true},{"title":"5g","offer_id":48087913496794,"sku":"TCI2510O049144897","price":6887000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510O0491.jpg?v=1767131980"},{"product_id":"tci2510t058551466","title":"TCI T0585 18156-74-6 N-Trimethylsilylimidazole [Trimethylsilylating Reagent]","description":"\u003cp\u003e\u003cstrong\u003eN-Trimethylsilylimidazole [Trimethylsilylating Reagent]\u003c\/strong\u003e (CAS 18156-74-6) is a high-quality chemical from TCI, supplied as \u003cstrong\u003eReagent Grade \/ for Synthesis\u003c\/strong\u003e.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eApplication:\u003c\/strong\u003e Used as a silylating reagent for hydroxyl-group protection and GC derivatisation.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eSpecifications:\u003c\/strong\u003e\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eMolecular formula: C6H12N2Si\u003c\/li\u003e\n\u003cli\u003eCAS number: 18156-74-6\u003c\/li\u003e\n\u003cli\u003ePurity: \u0026gt;98.0%(T)\u003c\/li\u003e\n\u003cli\u003eTCI product code: T0585\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003e\u003cstrong\u003eSynonyms:\u003c\/strong\u003e TMS-Imidazole; SIM; TMSI\u003c\/p\u003e\u003cp\u003eAvailable from \u003cstrong\u003eAMI Scientific\u003c\/strong\u003e, the authorised TCI distributor in Indonesia. \u003cstrong\u003eContact us for pricing and stock availability\u003c\/strong\u003e — we ship throughout Indonesia.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"25g","offer_id":48088329912538,"sku":"TCI2510T058551466","price":1715000.0,"currency_code":"IDR","in_stock":true},{"title":"100g","offer_id":48088329945306,"sku":"TCI2510T058551467","price":4189000.0,"currency_code":"IDR","in_stock":true},{"title":"250g","offer_id":48088329978074,"sku":"TCI2510T058551468","price":8124000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510T0585.jpg?v=1767140237"},{"product_id":"tci2510b454710844","title":"TCI B4547 866769-99-5 2,5-Bis(4-bromophenyl)-1,1-dimethyl-3,4-diphenylsilole","description":"\u003cp\u003e\u003cstrong\u003e2,5-Bis(4-bromophenyl)-1,1-dimethyl-3,4-diphenylsilole\u003c\/strong\u003e (CAS 866769-99-5) is a high-quality chemical from TCI, supplied as \u003cstrong\u003eGC Grade \/ for Synthesis\u003c\/strong\u003e.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eApplication:\u003c\/strong\u003e Synthesis reagent for a wide range of organic chemistry transformations in laboratory and industrial settings.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eSpecifications:\u003c\/strong\u003e\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eMolecular formula: C30H24Br2Si\u003c\/li\u003e\n\u003cli\u003eCAS number: 866769-99-5\u003c\/li\u003e\n\u003cli\u003ePurity: \u0026gt;95.0%(GC)\u003c\/li\u003e\n\u003cli\u003eTCI product code: B4547\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003e\u003cstrong\u003eSynonyms:\u003c\/strong\u003e 2,5-Bis(4-bromophenyl)-1,1-dimethyl-3,4-diphenylsilacyclopenta-2,4-diene\u003c\/p\u003e\u003cp\u003eAvailable from \u003cstrong\u003eAMI Scientific\u003c\/strong\u003e, the authorised TCI distributor in Indonesia. \u003cstrong\u003eContact us for pricing and stock availability\u003c\/strong\u003e — we ship throughout Indonesia.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48085800681690,"sku":"TCI2510B454710844","price":2812000.0,"currency_code":"IDR","in_stock":true},{"title":"5g","offer_id":48085800714458,"sku":"TCI2510B454710845","price":9585000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510B4547.jpg?v=1768204333"},{"product_id":"tci2510t170652980","title":"TCI T1706 18245-28-8 2-Trimethylsilylthiophene","description":"\u003cp\u003e\u003cstrong\u003e2-Trimethylsilylthiophene\u003c\/strong\u003e (CAS 18245-28-8) is a high-quality chemical from TCI, supplied as \u003cstrong\u003eGC Grade \/ for Synthesis\u003c\/strong\u003e.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eApplication:\u003c\/strong\u003e Used as a silylating reagent for hydroxyl-group protection and GC derivatisation.\u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eSpecifications:\u003c\/strong\u003e\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eMolecular formula: C7H12SSi\u003c\/li\u003e\n\u003cli\u003eCAS number: 18245-28-8\u003c\/li\u003e\n\u003cli\u003ePurity: \u0026gt;98.0%(GC)\u003c\/li\u003e\n\u003cli\u003eTCI product code: T1706\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003e\u003cstrong\u003eSynonyms:\u003c\/strong\u003e 2-Thienyltrimethylsilane\u003c\/p\u003e\u003cp\u003eAvailable from \u003cstrong\u003eAMI Scientific\u003c\/strong\u003e, the authorised TCI distributor in Indonesia. \u003cstrong\u003eContact us for pricing and stock availability\u003c\/strong\u003e — we ship throughout Indonesia.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"5g","offer_id":48088436637914,"sku":"TCI2510T170652980","price":2390000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510T1706_1e46d723-1a49-4ea8-9d91-fe2e1c54dac3.jpg?v=1768363313"}],"url":"https:\/\/amiscientific.com\/en\/collections\/tci-l4-organosilicon-compounds-other-organosilicon.oembed","provider":"AMI Scientific","version":"1.0","type":"link"}