{"title":"Phenanthrenes [Small Molecule Semiconductor Building Blocks]","description":"\u003cp\u003e\u003cstrong\u003ePhenanthrenes [Small Molecule Semiconductor Building Blocks]\u003c\/strong\u003e — berisi turunan hidrokarbon aromatik polisiklik fenantrena yang tersubstitusi gugus halogen, boronat, atau keton pada posisi tertentu di cincin aromatiknya. Struktur planar dan sistem elektron terkonjugasi pada senyawa ini menjadikannya blok bangunan penting untuk molekul semikonduktor organik.\u003c\/p\u003e\u003cp\u003ePhenanthrenes dipakai sebagai bahan awal dalam reaksi kopling silang berkatalis logam transisi, seperti Suzuki atau Negishi, untuk merakit molekul pemancar cahaya dan bahan transport muatan pada penelitian OLED serta elektronik organik lainnya. Turunan bromo dan asam boronatnya menjadi mitra kopling yang umum dipakai peneliti material semikonduktor.\u003c\/p\u003e\u003cp\u003eContoh produk dalam koleksi ini: \u003ca href=\"\/en\/products\/tci2510b467111018\"\u003eTCI B4671 62162-97-4 2-Bromophenanthrene\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b603712841\"\u003eTCI B6037 13292-05-2 3-Bromophenanthrene-9,10-dione\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b23878113\"\u003eTCI B2387 715-50-4 3-Bromophenanthrene\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b712813904\"\u003eTCI B7128 19462-79-4 4-Bromophenanthrene\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510b08385844\"\u003eTCI B0838 573-17-1 9-Bromophenanthrene\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510d469225364\"\u003eTCI D4692 53348-05-3 3,6-Dibromophenanthrene-9,10-dione\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510p109346671\"\u003eTCI P1093 68572-87-2 9-Phenanthreneboronic Acid (contains varying amounts of Anhydride)\u003c\/a\u003e, \u003ca href=\"\/en\/products\/tci2510d505025867\"\u003eTCI D5050 62325-30-8 2,7-Dibromophenanthrene\u003c\/a\u003e.\u003c\/p\u003e\u003cp\u003ePerhatikan posisi substitusi (2-, 3-, atau 9-) pada cincin fenantrena serta kemurnian bahan, dan untuk asam boronat perhatikan kemungkinan kandungan bentuk anhidridanya yang bervariasi. Seluruh produk merupakan produk asli Tokyo Chemical Industry (TCI) Jepang, dengan kemurnian, kemasan, dan kondisi penyimpanan tercantum pada halaman masing-masing item.\u003c\/p\u003e\u003cp\u003eKategori lain yang sejajar di bawah Small Molecule Semiconductor Building Blocks, sering dipakai bersamaan dalam satu alur kerja laboratorium:\u003c\/p\u003e\u003cul\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-carbazoles-small-molecule-semiconductor-building-blocks\"\u003eCarbazoles [Small Molecule Semiconductor Building Blocks]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-fluorenes-fluorenones-small-molecule-semiconductor-building-blocks\"\u003eFluorenes, Fluorenones [Small Molecule Semiconductor Building Blocks]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-thiophenes-small-molecule-semiconductor-building-blocks\"\u003eThiophenes [Small Molecule Semiconductor Building Blocks]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-anthracenes-anthraquinones-small-molecule-semiconductor-building-blocks\"\u003eAnthracenes, Anthraquinones [Small Molecule Semiconductor Building Blocks]\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-small-molecule-semiconductor-building-blocks-others\"\u003eSmall Molecule Semiconductor Building Blocks (Others)\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"\/en\/collections\/tci-l4-secondary-arylamines-small-molecule-semiconductor-building-blocks\"\u003eSecondary Arylamines [Small Molecule Semiconductor Building Blocks]\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ul\u003e\u003cp\u003eKembali ke \u003ca href=\"\/en\/collections\/tci-l3-small-molecule-semiconductor-building-blocks\"\u003eSmall Molecule Semiconductor Building Blocks\u003c\/a\u003e. Untuk pengadaan volume besar, kemasan khusus, atau grade tertentu, hubungi tim AMI Scientific — distributor resmi TCI Japan di Indonesia — untuk pengecekan ketersediaan dan lead time langsung ke Jepang.\u003c\/p\u003e","products":[{"product_id":"tci2510b603712841","title":"TCI B6037 13292-05-2 3-Bromophenanthrene-9,10-dione","description":"\u003ch3\u003eDescription\u003c\/h3\u003e\n\u003cp\u003e3-Bromophenanthrene-9,10-dione is a non-heterocyclic building block widely utilized as a key intermediate in the synthesis of substituted phenanthrene derivatives. It serves as a versatile precursor for cross-coupling reactions, selective oxidations, and further functional group modifications aimed at constructing complex molecular architectures. This compound finds applications in the development of functional organic materials, including dyes, fluorescent sensors, and organic semiconductors, owing to the dual reactivity conferred by its quinone moiety and bromo substituent.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48085916254426,"sku":"TCI2510B603712841","price":1490000.0,"currency_code":"IDR","in_stock":true},{"title":"5g","offer_id":48085916287194,"sku":"TCI2510B603712842","price":5172000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510B6037_3d359168-6d35-4dae-9dd2-7163fc8edc9d.jpg?v=1767864318"},{"product_id":"tci2510d469225364","title":"TCI D4692 53348-05-3 3,6-Dibromophenanthrene-9,10-dione","description":"\u003ch3\u003eDescription\u003c\/h3\u003e\n\u003cp\u003eTCI D4692, CAS 53348-05-3, is 3,6-Dibromophenanthrene-9,10-dione, a small molecule building block prepared for organic semiconductor research and materials science work. The compound is a phenanthrenequinone derivative: a three-ring phenanthrene framework carrying two adjacent ketone groups at the nine and ten positions, together with two bromine atoms placed at the three and six positions. The combination of an ortho-dione unit and two bromine sites makes it a highly useful starting material for constructing large conjugated molecules. In materials laboratories, it serves as an electron-accepting core that can be extended into a range of functional units for organic electronic devices.\u003c\/p\u003e\n\u003cp\u003eThe advantage that makes this compound a frequent choice lies in the two kinds of reactivity it offers at the same time, which can be used in sequence. The ortho-dione group condenses readily with aromatic diamines to form a pyrazine ring, producing strong acceptor units such as the dibenzo[a,c]phenazine framework that is popular in light-emitting materials. The two bromine atoms, meanwhile, act as ideal connection points for palladium-catalysed cross-coupling reactions, allowing donor arms, solubilising chains, or polymer segments to be attached to the core with good positional control.\u003c\/p\u003e\n\u003cp\u003eIn Indonesian laboratories, this building block is typically used by university and institutional research groups working on organic electronics, thin-film materials, and functional dye chemistry. It suits synthetic work carried out on a research scale, where a defined halogenated acceptor core is needed as the entry point to a longer synthetic sequence. Groups developing emitter materials, conjugated polymers, and small-molecule semiconductors commonly draw on this class of reagent when building and screening candidate structures.\u003c\/p\u003e\n\u003ch3\u003eLaboratory Applications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eDibenzo[a,c]phenazine synthesis: the adjacent nine and ten ketone groups condense directly with aromatic diamines, giving research groups a reliable route to strong acceptor frameworks used in light-emitting materials.\u003c\/li\u003e\n\u003cli\u003ePalladium-catalysed cross-coupling chemistry: the bromine atoms at the three and six positions serve as defined connection points for attaching aryl, donor, or solubilising fragments to the phenanthrene core.\u003c\/li\u003e\n\u003cli\u003eConjugated polymer building block work: the symmetric pair of bromine sites allows the molecule to be incorporated as a repeating acceptor segment within extended conjugated polymer chains.\u003c\/li\u003e\n\u003cli\u003eOrganic electronic device material development: the electron-accepting phenanthrenequinone core provides a starting scaffold for preparing small-molecule semiconductors intended for evaluation in device studies.\u003c\/li\u003e\n\u003cli\u003eSequential functionalisation studies: because the dione and the two bromine sites react under different conditions, researchers can carry out stepwise modification of one reactive site before addressing the other.\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eSpecifications\u003c\/h3\u003e\n\u003cul\u003e\n\u003cli\u003eBrand: TCI\u003c\/li\u003e\n\u003cli\u003eCAS number: 53348-05-3\u003c\/li\u003e\n\u003cli\u003eChemical name: 3,6-Dibromophenanthrene-9,10-dione\u003c\/li\u003e\n\u003cli\u003eCategory: Materials Science \u0026gt; Material Building Blocks \u0026gt; Small Molecule Semiconductor Building Blocks\u003c\/li\u003e\n\u003cli\u003ePack sizes: research-scale synthetic quantities; please confirm the available pack size when ordering\u003c\/li\u003e\n\u003cli\u003eStorage: keep in a closed original container under the conditions stated on the manufacturer label\u003c\/li\u003e\n\u003c\/ul\u003e\n\u003ch3\u003eHandling and Storage\u003c\/h3\u003e\n\u003cp\u003eStore the container tightly closed in a cool, dry, and well-ventilated area, away from direct sunlight, heat sources, and incompatible reagents, following the conditions given on the manufacturer label. Keep the material in its original supplier container, or in a clean, chemically compatible and properly labelled vessel if transfer is required. Handle the solid inside a fume hood, using a laboratory coat, safety glasses, and suitable chemical-resistant gloves, and avoid generating or inhaling dust during weighing and transfer. Close the container promptly after use, keep it clearly labelled, and consult the manufacturer safety data sheet before handling, storage, or waste disposal.\u003c\/p\u003e","brand":"TCI","offers":[{"title":"1g","offer_id":48086703833306,"sku":"TCI2510D469225364","price":3964000.0,"currency_code":"IDR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0756\/7156\/8602\/files\/TCI2510D4692.jpg?v=1771059007"}],"url":"https:\/\/amiscientific.com\/en\/collections\/tci-l4-phenanthrenes-small-molecule-semiconductor-building-blocks.oembed","provider":"AMI Scientific","version":"1.0","type":"link"}