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Description
5-(tert-Butyl)-2-hydroxybenzaldehyde (TCI B6598, CAS 2725-53-3) is a salicylaldehyde derivative bearing a bulky tert-butyl substituent at the 5-position. The adjacent hydroxyl and aldehyde groups make it a classic precursor for Schiff base formation with primary amines. Condensation with diamines gives salen- and salophen-type ligands that are widely used to prepare transition metal complexes for catalysis research. The scaffold is also popular in the design of fluorescent chemosensors, and the 5 g and 25 g packs cover both exploratory and routine ligand synthesis.
Scientific References
Inagaki et al. (2003). Short Synthesis of tert -Butyl-Hydroxylated 3,5-Di- tert -butyl-4-hydroxybenzaldehyde: Synthesis of tert -Butyl-Hydroxylated S-2474. The Journal of Organic Chemistrydoi:10.1021/jo020587v
FEDULINA et al. (1997). ChemInform Abstract: Reactivity of 3,5‐Di‐tert‐butyl‐4‐hydroxybenzaldehyde, 3,5‐Di‐tert‐ butyl‐4‐hydroxybenzylalcohol and 3,5‐Di‐tert‐butyl‐4‐hydroxybenzyl Methyl Ether in the Oxidation with Oxygen in Alkaline Solutions.. ChemInformdoi:10.1002/chin.199709057
Ribeiro da Silva et al. (2010). Thermodynamic study on hydroxybenzaldehyde derivatives: 3- and 4-Hydroxybenzaldehyde isomers and 3,5-di-tert-butyl-2-hydroxybenzaldehyde. The Journal of Chemical Thermodynamicsdoi:10.1016/j.jct.2009.10.009
References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.
