TCI B7045 (S,S)-4-tert-Butylphenyl-Tf-IDPi is a chiral imidodiphosphorimidate Brønsted acid catalyst developed for demanding asymmetric transformations. Its confined chiral pocket, built on a BINOL-derived scaffold bearing 4-tert-butylphenyl substituents, allows facial discrimination of small prochiral substrates. Researchers commonly evaluate it alongside other IDPi variants during catalyst screening and reaction optimization. Supplied in a 25 mg research-scale pack, it should be stored dry and handled under moisture-free conditions.
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- RUBAN et al. (1990). ChemInform Abstract: P‐(2,4,6‐Tri‐tert‐butylphenyl)amino‐P′‐(2,4,6‐tri‐tert‐butylphenyl)diphosphene.. ChemInform doi:10.1002/chin.199032227
- Ito et al. (2002). Preparation of 2,4-bis(2,4,6-tri-tert-butylphenyl)-1,3-diphosphacyclobutenes from 2-(2,4,6-tri-tert-butylphenyl)-1-phosphaethyne and alkyllithiums. Chemical Communications doi:10.1039/b204142c
- Hou et al. (1999). The surprising formation of structurally distorted ap-9-(o-tert-butylphenyl)-9-methylthiofluorene and its facile homolysis into sp-9-(o-tert-butylphenyl)-3-methylthiofluorene and sp-9-(o-tert-butylphenyl)fluorene. Canadian Journal of Chemistry doi:10.1139/v99-088
References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.
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