(-)-4-tert-Butyl-2,6-bis[(4S,5S)-4,5-tetramethylene-1-(2,4,6-trimethylbenzenesulfonyl)imidazolin-2-yl]phenol (contains 5% Dichloromethane at maximum) TCI B6146

Chemical Identity

CAS No.: 2102316-91-4
PubChem: CID 146680186·SID 468590938
Formula: C42H54N4O5S2
Molecular weight: 759.04 g/mol
Purity: >98.0%(HPLC)

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: 4-tert-butyl-2,6-bis[1-(2,4,6-trimethylphenyl)sulfonyl-3a,4,5,6,7,7a-hexahydrobenzimidazol-2-yl]phenol
SMILES: CC1=CC(=C(C(=C1)C)S(=O)(=O)N2C3CCCCC3N=C2C4=CC(=CC(=C4O)C5=NC6CCCCC6N5S(=O)(=O)C7=C(C=C(C=C7C)C)C)C(C)(C)C)C
InChIKey: PHCBOQYGQGLYIL-UHFFFAOYSA-N

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(-)-4-tert-Butyl-2,6-bis[(4S,5S)-4,5-tetramethylene-1-(2,4,6-trimethylbenzenesulfonyl)imidazolin-2-yl]phenol is a chiral bis(imidazoline) ligand designed for asymmetric synthesis applications. This compound features two (4S,5S)-configured imidazoline moieties attached to a tert-butyl-substituted phenol core, providing a well-defined chiral environment suitable for enantioselective catalytic reactions. It is commonly employed in asymmetric C-C and C-N bond-forming reactions and serves as a valuable tool in the development of new enantioselective synthetic methodologies.