Ru-MACHO(regR) (contains 5% Toluene at maximum) TCI R0136

Chemical Identity

CAS No.: 1295649-40-9
PubChem: CID 91972047·SID 253659542
Formula: C29H30ClNOP2Ru
Molecular weight: 607.0 g/mol

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: carbon monoxide;2-diphenylphosphanyl-N-(2-diphenylphosphanylethyl)ethanamine;hydride;ruthenium(2+);chloride
SMILES: [H-].[C-]#[O+].C1=CC=C(C=C1)P(CCNCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.[Cl-].[Ru+2]
InChIKey: AKLZFUOZPWNQJJ-UHFFFAOYSA-M

Rp 1.298.850,00

~~Rp 924.000,00~~ Rp 1.298.850,00

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Berat 200mg 1g

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Ru-MACHO (regR) is a metal-based catalyst compound widely used in chemical reactions, particularly in hydrogenation processes. This material is a complex mixture containing rhenium (Re) and possibly other metals, which provides high catalytic activity. Its role in the laboratory is to accelerate chemical reactions that require metal-based catalysts, such as the hydrogenation of hydrocarbons or oxidation reactions. Due to its reactivity, Ru-MACHO is highly valuable in the synthesis of both organic and inorganic compounds.

The properties that make Ru-MACHO a preferred choice include its stable complex structure, which allows for repeated use under various reaction conditions. It is also resistant to high temperatures and pressures, making it suitable for extreme environments. Additionally, its consistent chemical and physical properties ensure reliable performance in different experimental setups. The presence of up to 5% toluene in the formulation ensures safety during handling while maintaining its effectiveness.

In Indonesian laboratories, Ru-MACHO is commonly used in chemical research and material technology studies. It is frequently found in academic and industrial research settings where catalytic processes are essential. Its versatility and performance make it a key component in the development of new chemical products and processes.

Advantages (TCI brochure)

Catalyzes the hydrogenation of esters to alcohols
Applicable to various solvents (neat, methanol, THF, etc.)
Allows reduction of sterically-bulky substrates due to its thermal stability

TCI brochures (PDF)

Ruthenium Complex Catalysts for Hydrogenation of Esters to Alcohols 2024-10-28 · p. 1
Hydrogenation Catalysts 2025-11-10 · p. 2
Transition Metal Catalysts 2026-04-10 · p. 9

Related TCI products

Hydrogenation Reactions: Ru-MACHO is ideal for hydrogenation processes due to its high catalytic activity and stability under varying conditions.
Organic Synthesis: The compound is widely used in organic synthesis to facilitate complex chemical transformations efficiently.
Oxidation Reactions: Its ability to catalyze oxidation reactions makes it a valuable tool in the synthesis of various organic and inorganic compounds.
High-Temperature Processes: The material’s resistance to high temperatures makes it suitable for reactions requiring extreme thermal conditions.
Material Science Research: Ru-MACHO is employed in material science to develop new materials with enhanced properties through catalytic processes.

From the TCI brochure

Hydrogenation of esters to alcohols: 0.1 mol% catalyst, H2 5 MPa, NaOMe 0.1 eq., MeOH, 16 h

Brand	TCI
CAS number	1295649-40-9
Molecular formula	—
Purity	—
Category	Chemistry > Catalysis and Inorganic Chemistry > Hydrogenation [Catalysis]
Pack sizes	—
Physical form	—
Storage	—

Data from the TCI brochure

Yield aromatic methyl ester substrate to alcohol	90% (0.1 mol% R0136, H2 5 MPa, NaOMe 0.1 eq., MeOH, 16 h)
Yield ester substrate with benzyloxy group to alcohol	92% (0.1 mol% R0136, H2 5 MPa, NaOMe 0.1 eq., MeOH, 16 h)
Yield N-heterocyclic ester substrate to alcohol	86% (0.1 mol% R0136, H2 5 MPa, NaOMe 0.1 eq., MeOH, 16 h)
Yield sterically bulky ester substrate to alcohol	98% (0.1 mol% R0136, H2 5 MPa, NaOMe 0.1 eq., MeOH, neat, 150 °C, 2 h)

Source: TCI brochure RR033 (2024-10-28)

Ru-MACHO should be stored in a cool, dry place away from direct sunlight and sources of heat. It is recommended to use airtight containers to prevent exposure to moisture and air, which may affect its stability. Due to the presence of toluene, it should be handled with care, using appropriate personal protective equipment such as gloves and safety goggles. The material is not flammable but should be kept away from incompatible substances. Regular inspection of storage conditions is advised to ensure the integrity of the compound. Proper labeling and storage practices are essential to maintain safety and effectiveness in laboratory environments.

References cited in the TCI brochure

Wataru Kuriyama. Catalytic Hydrogenation of Esters. Development of an Efficient Catalyst and Processes for Synthesising ( R )-1,2-Propanediol and 2-( l -Menthoxy)ethanol Organic Process Research & Development, 2011. doi:10.1021/op200234j