Ru-MACHO(regR)-BH TCI R0137

Chemical Identity

Other names: Ru-MACHO®-BH
CAS No.: 1295649-41-0
PubChem: CID 91972048·SID 253659543
Formula: C29H30BNOP2Ru
Molecular weight: 582.4 g/mol

Full identifiers (IUPAC, SMILES, InChIKey)

SMILES: [H-].[B-].[C-]#[O+].C1=CC=C(C=C1)P(CCNCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.[Ru+2]
InChIKey: DSVGRZDQKCWIMC-UHFFFAOYSA-N

Rp 1.298.850,00

~~Rp 924.000,00~~ Rp 1.298.850,00

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Berat 200mg 1g

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Ru-MACHO(regR)-BH is a metal-based catalyst widely used in laboratory hydrogenation reactions. As a key component in catalytic processes, it plays a vital role in accelerating chemical reactions without being consumed in the final product. This compound belongs to the class of metal-organic complexes, which are known for their ability to facilitate chemical transformations efficiently. Its application spans various fields of chemistry, particularly in organic synthesis and reduction reactions where hydrogenation is essential.

The unique properties of Ru-MACHO(regR)-BH make it a preferred choice for researchers. Its reactive nature allows it to interact effectively with substrates, enhancing the efficiency of hydrogenation processes. The complex structure of the compound ensures optimal performance in catalytic reactions, making it suitable for both academic and industrial research. Additionally, its stability under controlled laboratory conditions ensures consistent results, while its reactivity supports the development of new chemical methodologies.

In Indonesian laboratories, Ru-MACHO(regR)-BH is commonly used in scientific and industrial research, especially in organic chemistry and catalysis. Its effectiveness in promoting hydrogenation reactions has made it a valuable tool for researchers aiming to develop sustainable and efficient chemical processes. The compound’s reliability and performance contribute to the advancement of chemical technologies in the country.

Advantages (TCI brochure)

Catalyzes the hydrogenation of esters to alcohols
Applicable to various solvents (neat, methanol, THF, etc.)
Allows reduction of sterically-bulky substrates due to its thermal stability
No need to add base when using R0137

TCI brochures (PDF)

Ruthenium Complex Catalysts for Hydrogenation of Esters to Alcohols 2024-10-28 · p. 1
Iridium Catalyst for Hydrogenolysis of Urea Derivatives to Formamides and Amines under Mild Conditions 2024-01-25 · p. 1
Hydrogenation Catalysts 2025-11-10 · p. 2
Transition Metal Catalysts 2026-04-10 · p. 8
Boron Compounds 2025-10-07 · p. 23

Related TCI products

Hydrogenation Reactions: Ru-MACHO(regR)-BH is ideal for hydrogenation due to its ability to efficiently catalyze the addition of hydrogen to unsaturated compounds.
Organic Synthesis: This catalyst is well-suited for organic synthesis applications where controlled hydrogenation is required to produce specific chemical structures.
Reduction Processes: It supports various reduction reactions, making it a versatile tool in synthetic chemistry and industrial applications.
Catalytic Research: Its performance in catalytic systems makes it a preferred choice for studying reaction mechanisms and optimizing catalytic efficiency.
Sustainable Chemistry: The compound’s effectiveness in promoting efficient reactions aligns with the goals of sustainable and green chemistry practices.

From the TCI brochure

Hydrogenation of esters to alcohols: 0.1 mol% catalyst, H2 5 MPa, THF, 80 °C, 16 h

Brand	TCI
CAS number	1295649-41-0
Molecular formula	—
Purity	—
Category	Chemistry > Catalysis and Inorganic Chemistry > Hydrogenation [Catalysis]
Pack sizes	—
Physical form	—
Storage	Store in a cool, dry place away from moisture and direct sunlight

Data from the TCI brochure

Yield phenyl-substituted ester substrate to alcohol	77% (0.1 mol% R0137, H2 5 MPa, THF, 80 °C, 16 h)
Yield N-Boc amino ester substrate to alcohol	78% (0.1 mol% R0137, H2 5 MPa, THF, 80 °C, 16 h)
Yield N-Cbz amino lactone substrate to alcohol	88% (0.1 mol% R0137, H2 5 MPa, THF, 80 °C, 16 h)
Yield dioxolane diester substrate to alcohol	93% (0.1 mol% R0137, H2 5 MPa, THF, 80 °C, 16 h)
Δee (%) phenyl-substituted ester substrate	<1 (0.1 mol% R0137, H2 5 MPa, THF, 80 °C, 16 h; Δee = ee substrate − ee product)
Δee (%) N-Boc amino ester substrate	<1 (0.1 mol% R0137, H2 5 MPa, THF, 80 °C, 16 h; Δee = ee substrate − ee product)
Δee (%) N-Cbz amino lactone substrate	2 (0.1 mol% R0137, H2 5 MPa, THF, 80 °C, 16 h; Δee = ee substrate − ee product)
Δee (%) dioxolane diester substrate	<1 (0.1 mol% R0137, H2 5 MPa, THF, 80 °C, 16 h; Δee = ee substrate − ee product)

Source: TCI brochure RR033 (2024-10-28)

Ru-MACHO(regR)-BH should be stored in a cool, dry environment to maintain its chemical stability. It is recommended to use airtight containers to prevent exposure to moisture and air, which could affect its performance. Due to its reactive nature, it should be handled with care, using appropriate personal protective equipment such as gloves and safety goggles. Avoid contact with incompatible substances and ensure proper ventilation in the laboratory. Regular monitoring of storage conditions is advised to ensure the compound remains effective for its intended applications. Proper handling and storage practices are essential to maintain the integrity and efficiency of this catalyst in laboratory settings.

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