(R,R)-Ts-DENEB(regR) (CAS 1333981-84-2) is a high-quality chemical from TCI, supplied as Reagent Grade.
Application: Synthesis reagent for a wide range of organic chemistry transformations in laboratory and industrial settings.
Specifications:
- Molecular formula: C31H33ClN2O3RuS
- CAS number: 1333981-84-2
- TCI product code: T3078
Synonyms: Chloro[(R,R)-N-[2-[2-(4-methylbenzyloxy)ethyl]amino-1,2-diphenylethyl]-p-toluenesulfonamide]ruthenium(II); Chloro[(R,R)-N-[2-(4-methylbenzyloxy)ethyl]-N'-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
Available from AMI Scientific, the authorised TCI distributor in Indonesia. Contact us for pricing and stock availability — we ship throughout Indonesia.
Advantages (TCI brochure)
- Reduces carbonyl groups selectively
- Requires no high pressure equipment by using formic acid or IPA as a hydrogen source
TCI brochures (PDF)
- Ruthenium Complex Catalysts for Asymmetric Transfer Hydrogenation of Ketons 2026-01-30 · p. 1
- Hydrogenation Catalysts 2025-11-10 · p. 5
Related TCI products
- TCI T3077 1384974-37-1 (S,S)-Ts-DENEB(regR)
- TCI B3067 132071-87-5 [(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
- TCI R0171 374067-49-9 Ru(OAc)2[(S)-xylbinap]
- TCI R0170 374067-50-2 Ru(OAc)2[(R)-xylbinap]
- TCI R0159 944451-33-6 [RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl
- TCI R0155 944451-29-0 [RuCl(p-cymene)((S)-segphos(regR))]Cl
From the TCI brochure
- Asymmetric transfer hydrogenation of ketones
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Data from the TCI brochure
| time | 3 h (substrate 1 (aryl methyl ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
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| % yield | >99 (substrate 1 (aryl methyl ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| % ee | 98 (R) (substrate 1 (aryl methyl ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| time | 5 h (substrate 2 (alpha-chloro aryl ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| % yield | >99 (substrate 2 (alpha-chloro aryl ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| % ee | 97 (S) (substrate 2 (alpha-chloro aryl ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| time | 5 h (substrate 3 (alpha-hydroxy aryl ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| % yield | 98 (substrate 3 (alpha-hydroxy aryl ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| % ee | 96 (S) (substrate 3 (alpha-hydroxy aryl ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| time | 5 h (substrate 4 (bicyclic chromanone-type ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| % yield | >99 (substrate 4 (bicyclic chromanone-type ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| % ee | >99 (R) (substrate 4 (bicyclic chromanone-type ketone), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| time | 5 h (substrate 5 (heteroaryl methyl ketone, furan type), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| % yield | >99 (substrate 5 (heteroaryl methyl ketone, furan type), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
| % ee | 98 (R) (substrate 5 (heteroaryl methyl ketone, furan type), 0.1 mol% T3078, Et3N, HCO2H, 60 ºC) |
Source: TCI brochure RR034 (2026-01-30)
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References cited in the TCI brochure
- Taichiro Touge. Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H2 Hydrogenation Journal of the American Chemical Society, 2011. doi:10.1021/ja207283t
Product Categories
- Asymmetric SynthesisChiral Catalysts, Chiral Ligands, Chiral ReagentsHydrogenation [Asymmetric Synthesis]
- Catalysis and Inorganic ChemistryHydrogenation [Catalysis]Asymmetric Hydrogenation Catalysts
- Catalysis and Inorganic ChemistryTransition Elements [Catalysis and Inorganic Chemistry]Ruthenium [Catalysis and Inorganic Chemistry]


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