TCI
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Description
TCI C0799 o-Cymene (CAS 527-84-4) is the ortho isomer of cymene, available from AMI Scientific in a 0.1 mL research size. The adjacent methyl and isopropyl groups create a distinctive steric environment that makes it useful in studies of steric influence on reactivity. Analytical laboratories rely on it as an isomer reference for chromatographic identification and method validation. Store it tightly closed in a cool, well-ventilated area and follow the official TCI Safety Data Sheet.
Scientific References
- PANDIAKUMAR et al. (2015). Synthesis and unexpected reactivity of [Ru(η 6-cymene)Cl2(PPh2Cl)], leading to [Ru(η 6-cymene)Cl2(PPh2H)] and [Ru(η 6-cymene)Cl 2 (PPh2OH)] complexes. Journal of Chemical Sciences doi:10.1007/s12039-015-0905-z
- Herberhold et al. (2000). The 16-electron dithiolene complexes (p-cymene)M[S2C2(B10H10)] (M=Ru, Os) containing both η6-(p-cymene) and η2-(ortho-carborane-dithiolate): adduct formation with Lewis bases, and X-ray crystal structures of (p-cymene)Ru[S2C2(B10H10)](L) (L=PPh3) and {(p-cymene)Ru[S2C2(B10H10)]}2(μ-LL) (LL=Ph2PCH2CH2PPh2 and N2H4). Journal of Organometallic Chemistry doi:10.1016/s0022-328x(99)00692-0
- Lalrempuia et al. (2004). Study of reactivity ofp-cymene ruthenium(II) dimer towards diphenyl-2-pyridylphosphine: Synthesis, characterization and molecular structures of [(η6-p-cymene)RuCl2(PPh2Py)] and [(η6-p-cymene)RuCl(PPh2Py)]BF4. Journal of Chemical Sciences doi:10.1007/bf02708209
References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.
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