• (1S,2S)-(+)-1,2-Cyclohexanediamine (CAS 21436-03-3) - TCI C1448 - AMI Scientific
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TCI

CAS 21436-03-3

(1S,2S)-(+)-1,2-Cyclohexanediamine TCI C1448

(1S,2S)-(+)-1,2-Cyclohexanediamine TCI C1448
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Rp 4.028.850,00
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TCI C1448 (1S,2S)-(+)-1,2-Cyclohexanediamine (CAS 21436-03-3) is the enantiomeric counterpart of the widely used trans-1,2-diaminocyclohexane scaffold. It allows researchers to reverse the sense of chiral induction while keeping the same catalytic system, giving access to either product enantiomer. Typical uses include salen and Schiff base ligand synthesis, transition metal complexation, and hydrogen-bonding organocatalysts. AMI Scientific offers this TCI product in 5 g and 25 g packs, to be handled under the manufacturer's recommended inert and dry conditions.

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  • Garbutcheon-Singh et al. (2016). Synthesis, characterisation and cytotoxicity of [(1,10-phenanthroline)(1R,2R,4R/1S,2S,4S)-4-methyl-1,2-cyclohexanediamine)platinum(II)]2+ (PHEN-4-MeDACH). Inorganica Chimica Acta doi:10.1016/j.ica.2015.10.048
  • Zhang et al. (2010). Fixed helical Cd(II) coordination polymers assembled from diastereopure Schiff-base ligands derived from condensation of acetylacetone with 1S,2S- and 1R,2R-cyclohexanediamine. Inorganic Chemistry Communications doi:10.1016/j.inoche.2010.05.015
  • Kaizaki et al. (1998). First solid state synthesis of the racemic compound and enantiomer of dinuclear Λ,Λ-di-μ-hydroxo-bis [bis((1S,2S)-1,2-transcyclohexanediamine)chromium(III)] and Δ,Δ-di-μ-hydroxo-bis [bis((1R, 2R)-1,2-trans-cyclohexanediamine) chromium (III)] bromides. Inorganica Chimica Acta doi:10.1016/s0020-1693(97)06093-3

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