(1S,2S)-(+)-1,2-Cyclohexanediamine TCI C1448

Chemical Identity

Other names: (1S)-(+)-trans-1,2-Diaminocyclohexane
CAS No.: 21436-03-3
PubChem: CID 479307·SID 87566449
Formula: C6H14N2
Molecular weight: 114.19 g/mol
Purity: >98.0%(GC)(T)
Storage: 0-10°C
Reference databases: ChemSpider·ECHA

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: trans-(1S,2S)-cyclohexane-1,2-diamine
SMILES: C1CCC(C(C1)N)N
InChIKey: SSJXIUAHEKJCMH-WDSKDSINSA-N
MDL: MDL00062986

Rp 4.081.350,00

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Berat 5g 25g

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TCI C1448 (1S,2S)-(+)-1,2-Cyclohexanediamine (CAS 21436-03-3) is the enantiomeric counterpart of the widely used trans-1,2-diaminocyclohexane scaffold. It allows researchers to reverse the sense of chiral induction while keeping the same catalytic system, giving access to either product enantiomer. Typical uses include salen and Schiff base ligand synthesis, transition metal complexation, and hydrogen-bonding organocatalysts. AMI Scientific offers this TCI product in 5 g and 25 g packs, to be handled under the manufacturer's recommended inert and dry conditions.

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Garbutcheon-Singh et al. (2016). Synthesis, characterisation and cytotoxicity of [(1,10-phenanthroline)(1R,2R,4R/1S,2S,4S)-4-methyl-1,2-cyclohexanediamine)platinum(II)]2+ (PHEN-4-MeDACH). Inorganica Chimica Acta doi:10.1016/j.ica.2015.10.048
Zhang et al. (2010). Fixed helical Cd(II) coordination polymers assembled from diastereopure Schiff-base ligands derived from condensation of acetylacetone with 1S,2S- and 1R,2R-cyclohexanediamine. Inorganic Chemistry Communications doi:10.1016/j.inoche.2010.05.015
Kaizaki et al. (1998). First solid state synthesis of the racemic compound and enantiomer of dinuclear Λ,Λ-di-μ-hydroxo-bis [bis((1S,2S)-1,2-transcyclohexanediamine)chromium(III)] and Δ,Δ-di-μ-hydroxo-bis [bis((1R, 2R)-1,2-trans-cyclohexanediamine) chromium (III)] bromides. Inorganica Chimica Acta doi:10.1016/s0020-1693(97)06093-3

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.