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TCI

CAS 107869-45-4

(+)-10-Camphorsulfonimine TCI C1391

(+)-10-Camphorsulfonimine TCI C1391

Chemical Identity

Other names
(7R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0(1,5)]dec-4-ene 3,3-Dioxide · (3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-Dioxide
CAS No.
107869-45-4
Formula
C10H15NO2S
Molecular weight
213.30 g/mol
Purity
>97.0%(N)
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
(7R)-10,10-dimethyl-3lambda6-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-dioxide
SMILES
CC1(C2CCC13CS(=O)(=O)N=C3C2)C
InChIKey
ZAHOEBNYVSWBBW-PVSHWOEXSA-N
MDL
MDL00013315
PubChem
CID 44630210
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TCI C1391 (+)-10-Camphorsulfonimine (CAS 107869-45-4) is a chiral building block derived from the rigid camphor framework and used in asymmetric synthesis. Its sulfonimine group is most commonly oxidised to the corresponding camphor-derived oxaziridine, a well-established reagent for enantioselective oxygen transfer. Typical applications include asymmetric hydroxylation of enolates and the preparation of chiral sulfoxides from sulfides. AMI Scientific supplies the (+)-enantiomer in a 5 g pack, complementing the (-)-form for researchers who need access to both product configurations.

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