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TCI

CAS 60886-80-8

(-)-10-Camphorsulfonimine TCI C1393

(-)-10-Camphorsulfonimine TCI C1393

Chemical Identity

Other names
(7S)-(-)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0(1,5)]dec-4-ene 3,3-Dioxide · (3aS)-(-)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-Dioxide
CAS No.
60886-80-8
Formula
C10H15NO2S
Molecular weight
213.30 g/mol
Purity
>98.0%(HPLC)(N)
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
(1S,7R)-10,10-dimethyl-3lambda6-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-dioxide
SMILES
CC1(C2CCC13CS(=O)(=O)N=C3C2)C
InChIKey
ZAHOEBNYVSWBBW-GMSGAONNSA-N
MDL
MDL00064576
PubChem
CID 719802
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TCI C1393 (-)-10-Camphorsulfonimine (CAS 60886-80-8) is the opposite enantiomer of the camphor-derived sulfonimine used in asymmetric synthesis. Oxidation of its imine group affords a camphor-based oxaziridine that transfers oxygen with defined stereochemical preference. It is applied in enantioselective α-hydroxylation of carbonyl compounds and in the asymmetric oxidation of sulfides to chiral sulfoxides. Available from AMI Scientific in a 5 g pack, it lets researchers select the product configuration required by their synthetic route.

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