(-)-10-Camphorsulfonimine TCI C1393

Chemical Identity

Other names: (7S)-(-)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0(1,5)]dec-4-ene 3,3-Dioxide · (3aS)-(-)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-Dioxide
CAS No.: 60886-80-8
PubChem: CID 719802·SID 87566403
Formula: C10H15NO2S
Molecular weight: 213.30 g/mol
Purity: >98.0%(HPLC)(N)

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: (1S,7R)-10,10-dimethyl-3lambda6-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-dioxide
SMILES: CC1(C2CCC13CS(=O)(=O)N=C3C2)C
InChIKey: ZAHOEBNYVSWBBW-GMSGAONNSA-N
MDL: MDL00064576

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Berat 5g

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TCI C1393 (-)-10-Camphorsulfonimine (CAS 60886-80-8) is the opposite enantiomer of the camphor-derived sulfonimine used in asymmetric synthesis. Oxidation of its imine group affords a camphor-based oxaziridine that transfers oxygen with defined stereochemical preference. It is applied in enantioselective α-hydroxylation of carbonyl compounds and in the asymmetric oxidation of sulfides to chiral sulfoxides. Available from AMI Scientific in a 5 g pack, it lets researchers select the product configuration required by their synthetic route.