TCI C0274 Allyl Chloride (CAS 107-05-1) is a highly reactive allylic halide and one of the most widely used allylating agents in organic synthesis. It introduces the allyl group onto oxygen, nitrogen, sulfur, and carbon nucleophiles, and serves as a precursor to epichlorohydrin and allyl organometallic reagents. The resulting allyl group can be further elaborated through metathesis, epoxidation, hydroboration, or used as a removable protecting group. Supplied in 25 mL and 500 mL packs, it is a flammable, toxic, and strongly irritating liquid that must be handled in a fume hood.
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- Zulfiqar et al. (1999). Effect of allyl chloride comonomer on the thermal degradation of poly(methyl methacrylate-co-allyl chloride). Polymer Degradation and Stability doi:10.1016/s0141-3910(99)00087-7
- Yadav et al. (2004). Acetyl Chloride—Ethanol Brings About a Remarkably Efficient Conversion of Allyl Acetates into Allyl Chlorides.. ChemInform doi:10.1002/chin.200410041
- Yadav et al. (2003). Acetyl chloride–ethanol brings about a remarkably efficient conversion of allyl acetates into allyl chlorides. Tetrahedron doi:10.1016/j.tet.2003.09.063
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