Allyl Chloride TCI C0274

Chemical Identity

Other names: 3-Chloro-1-propene
CAS No.: 107-05-1
PubChem: CID 7850·SID 87565428
Formula: C3H5Cl
Molecular weight: 76.52 g/mol
Purity: >98.0%(GC)
Storage: <0°C
Reference databases: ChEBI·ChemSpider·ECHA·Wikipedia

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: 3-chloroprop-1-ene
SMILES: C=CCCl
InChIKey: OSDWBNJEKMUWAV-UHFFFAOYSA-N
MDL: MDL00000984

Rp 477.750,00

~~Rp 333.900,00~~ Rp 477.750,00

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Volume 25mL 500mL

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TCI C0274 Allyl Chloride (CAS 107-05-1) is a highly reactive allylic halide and one of the most widely used allylating agents in organic synthesis. It introduces the allyl group onto oxygen, nitrogen, sulfur, and carbon nucleophiles, and serves as a precursor to epichlorohydrin and allyl organometallic reagents. The resulting allyl group can be further elaborated through metathesis, epoxidation, hydroboration, or used as a removable protecting group. Supplied in 25 mL and 500 mL packs, it is a flammable, toxic, and strongly irritating liquid that must be handled in a fume hood.

TCI brochures (PDF)

Protecting Agents 2025-03-25 · p. 10

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Zulfiqar et al. (1999). Effect of allyl chloride comonomer on the thermal degradation of poly(methyl methacrylate-co-allyl chloride). Polymer Degradation and Stability doi:10.1016/s0141-3910(99)00087-7
Yadav et al. (2004). Acetyl Chloride—Ethanol Brings About a Remarkably Efficient Conversion of Allyl Acetates into Allyl Chlorides.. ChemInform doi:10.1002/chin.200410041
Yadav et al. (2003). Acetyl chloride–ethanol brings about a remarkably efficient conversion of allyl acetates into allyl chlorides. Tetrahedron doi:10.1016/j.tet.2003.09.063

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.