Sorotan Produk TCI

Phthalimide-Containing Acrylic Monomers for Postpolymerization Modification

Phthalimide-Containing Acrylic Monomers for Pos...

N-phthalimidyl acrylate and methacrylate monomers for postpolymerization modification: SET reduction, decarboxylation, and RPC phosphonylation.

Phthalimide-Containing Acrylic Monomers for Pos...

N-phthalimidyl acrylate and methacrylate monomers for postpolymerization modification: SET reduction, decarboxylation, and RPC phosphonylation.

Application scheme: synthesis of p-toluidine derivatives from o-tolylboronic acid using A3838 with R-N(SiMe3)2 in EtOH/MeCN, giving the R=H reagent A3839, then Cs2CO3/THF with p-tolylboronic acid giving the p-toluidine product, Y. 84% (R=H from A3839).

Hypervalent Iodine Reagents Enable Metal-Free A...

Hypervalent iodine reagents A3838 and A3839 enable metal-free electrophilic amination of aromatic boronic acids, with yields of 84% and 87% in the examples.

Hypervalent Iodine Reagents Enable Metal-Free A...

Hypervalent iodine reagents A3838 and A3839 enable metal-free electrophilic amination of aromatic boronic acids, with yields of 84% and 87% in the examples.

Scheme for introduction of secondary alkyl groups at the meta-position using cat. C3456 and K2CO3 [P1748] in dioxane at 100 °C, with pyridine as directing group.

Ruthenium Catalyst for C-H Activation at the me...

Ruthenium catalyst (p-Cymene)bis(mesitylcarboxylato)ruthenium(II) [C3456] for meta-selective and decarboxylative C-H functionalization on arenes.

Ruthenium Catalyst for C-H Activation at the me...

Ruthenium catalyst (p-Cymene)bis(mesitylcarboxylato)ruthenium(II) [C3456] for meta-selective and decarboxylative C-H functionalization on arenes.

Application scheme: copolymerization of phthalimidyl (meth)acrylate with acrylate, then CO2/phthalimide derivative step and post-polymerization modifications (H+, nitroxide-type reagent, photocatalytic phosphorus reagent) referenced to Ref. 1-4.

Acrylate Monomers for Converting Polymer Backbo...

N-Phthalimidyl Acrylate (P3351) and Methacrylate (P3350) monomers for post-polymerization modification, converting polymer backbones to ethylene or propylene.

Acrylate Monomers for Converting Polymer Backbo...

N-Phthalimidyl Acrylate (P3351) and Methacrylate (P3350) monomers for post-polymerization modification, converting polymer backbones to ethylene or propylene.

Intermediate Salt for Mitsunobu-Type SN2 Reactions with Lower Acidic Amines

Intermediate Salt for Mitsunobu-Type SN2 Reacti...

BEHT triflate [B7082], a bench-stable Mitsunobu intermediate for SN2 reactions with less acidic amines; example with indoline gives 54% yield.

Intermediate Salt for Mitsunobu-Type SN2 Reacti...

BEHT triflate [B7082], a bench-stable Mitsunobu intermediate for SN2 reactions with less acidic amines; example with indoline gives 54% yield.

Organic Photoredox Catalyst for Metal-Free Polymer Synthesis by O-ATRP and PET-RAFT

Organic Photoredox Catalyst for Metal-Free Poly...

Peri-Xanthenoxanthene (X0083): visible-light organic photoredox catalyst (443 nm) for metal-free O-ATRP and PET-RAFT polymerization at low catalyst loading.

Organic Photoredox Catalyst for Metal-Free Poly...

Peri-Xanthenoxanthene (X0083): visible-light organic photoredox catalyst (443 nm) for metal-free O-ATRP and PET-RAFT polymerization at low catalyst loading.