Collection: Silyl Enol Ethers, Silyl Ketene Acetals [Organosilicon]

Silyl Enol Ethers, Silyl Ketene Acetals [Organosilicon] — covers silyl enol ethers and silyl ketene acetals, namely enol or enolate derivatives of ketones and esters whose hydroxyl or oxygen groups are protected as trimethylsilyl ethers. This structure functions as a neutral enolate equivalent that is stable during storage.

Silyl Enol Ethers and Silyl Ketene Acetals are used as nucleophiles in Mukaiyama aldol reactions and Mukaiyama-Michael reactions for carbon-carbon bond formation in organic synthesis. Total synthesis and organic chemistry researchers utilize the E or Z geometry of these compounds to control the stereochemistry of the resulting aldol products.

Example products in this collection: TCI T4325 6651-34-9 Trimethyl[(2-methylprop-1-en-1-yl)oxy]silane, TCI B5597 194233-66-4 trans-3-(tert-Butyldimethylsilyloxy)-N,N-dimethyl-1,3-butadiene-1-amine, TCI T2561 6213-94-1 Trimethyl(vinyloxy)silane, TCI B5878 77086-38-5 1-(tert-Butyldimethylsilyloxy)-1-methoxyethene, TCI T1469 38053-91-7 2-Trimethylsilyloxy-1,3-butadiene, TCI D1789 31469-15-5 Dimethylketene Methyl Trimethylsilyl Acetal, TCI B3298 72658-10-7 (1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene, TCI M0759 59414-23-2 1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene.

Pay attention to the isomer geometry (E or Z) of the double bond as well as the purity and stability of the material during storage, because these compounds can hydrolyze back to their original carbonyl when exposed to moisture. All products are genuine products of Tokyo Chemical Industry (TCI) Japan, with purity, packaging, and storage conditions listed on each item's page.

Other categories at the same level under Organosilicon [Organometallic Reagents], often used together in one laboratory workflow:

• Organosilicon Compounds (Other) [Organosilicon]
• Trialkoxysilanes [Organosilicon]
• Hydrosilanes [Organosilicon]
• Siloxanes [Organosilicon]
• Ethynylsilanes [Organosilicon]
• Clorosilanes [Organosilicon]

Back to Organosilicon [Organometallic Reagents]. For large-volume procurement, special packaging, or particular grades, contact the AMI Scientific team — the official TCI Japan distributor in Indonesia — to check availability and lead time directly from Japan.