Electrodeposition & Electroplating

Electrochemistry/Electrodeposition & ElectroplatingPotentiostat applications

Electrodeposition and Electroplating with a Potentiostat

A potentiostat gives full control over potential, current and pulse shape when depositing metals, alloys, oxides or conductive polymers. This page covers techniques, thickness calculations and equipment from small samples to high currents.

  • Potentiostatic & galvanostaticplus multi-step and pulse
  • Up to ±100 Awith Corrtest boosters
  • Up to ±50 VCS5010B booster
  • Test the coatingTafel and EIS on the same instrument

Why a potentiostat rather than a plain power supply?

A DC power supply only sets the cell current or voltage roughly. A potentiostat controls the working electrode potential against a reference, so the reaction can be chosen precisely: for example depositing copper without evolving hydrogen, or tuning alloy composition. Pulse techniques refine grain size and reduce residual stress in the coating.

For larger areas, Corrtest boosters raise the current to ±20, 50 or 100 A, or the voltage to ±50 V. The Corrtest brochure cites power batteries, electrolysis and electrodeposition as the applications.

Deposition techniques

Technique How it works Best for
Preliminary CV Finds metal reduction potential and the hydrogen evolution limit First step for any new system
Potentiostatic (chronoamperometry) Fixed potential; current recorded over time Nucleation, nanostructures, phase control
Galvanostatic (chronopotentiometry) Fixed current; thickness easily calculated from charge Metal plating, thick layers
Multi-step potential / current Several steps in sequence in one programme Layered coatings, nucleation then growth
Pulse plating Current or potential switched on and off repeatedly Fine grains, alloys, uniform layers
Electropolymerisation Repeated CV or fixed potential in monomer solution Polypyrrole, PEDOT, polyaniline for sensors and supercapacitors

Calculating coating thickness

Faraday's lawm = (Q · M) / (z · F) · η Q = I · tm = deposited mass (g), M = molar mass (g/mol), z = electrons per ion, F = 96485 C/mol, η = current efficiency.
Average thicknessd = m / (ρ · A)ρ = metal density (g/cm³), A = area (cm²). Example: copper (M = 63.55; z = 2; ρ = 8.96) at 10 mA/cm² for 10 minutes with η = 100% gives about 2.2 µm.

Models and boosters

Product Best for Price Purchase
Corrtest CS350M (EIS to 1 MHz, ±2 A) Lab-sample deposition up to ±2 A; booster-ready. Rp 167.884.000 Buy online
Corrtest CS1350Pro (±5 A) Up to ±5 A without a booster. Rp 183.885.000 Buy online
Corrtest CS2020B 20 A current booster Up to ±20 A for larger areas. Rp 132.425.000 Buy online
Corrtest CS5010B 10 A / 50 V booster Up to ±50 V for high-resistance electrolytes or anodising. Rp 300.985.000 Buy online

Store catalogue prices before 11% VAT and shipping; subject to change. Stock and delivery time are confirmed in the quotation.

Cells and accessories

Accessory Purpose Price Purchase
CS935 electrolytic cell 50/100 mL Lab-scale plating bath Rp 2.204.000 Buy online
CS931 jacketed cell 50 mL Bath temperature control Rp 3.030.000 Buy online
CS945 specimen clamp Holds thin plates (< 1 mm) as the working electrode Rp 4.076.000 Buy online
CS911 platinum plate 20 × 20 mm Inert anode Rp 7.849.000 Buy online
CS900 SCE Reference electrode Rp 2.066.000 Buy online
CS924 copper working electrode Test substrate Rp 2.617.000 Buy online

Store catalogue prices before 11% VAT and shipping; subject to change. Stock and delivery time are confirmed in the quotation.

Frequently asked questions

When do I need a current booster?

When total current exceeds the potentiostat's rating. Example: 20 mA/cm² on a 10 × 10 cm plate needs 2 A, the limit of a ±2 A model; larger areas need a booster.

Can a potentiostat be used for anodising?

Yes, at sample scale. Anodising aluminium or titanium often needs tens of volts, so the CS5010B booster (±50 V) is relevant.

Can I test the coating with the same instrument?

Yes. Corrosion-test the coating with Tafel and EIS on the same potentiostat. See corrosion and coating testing.

Need help choosing?

Tell us about your samples, methods and budget. Our team will put together the equipment and supplies with a formal quotation.