Astatine (At): Electron Configuration, Properties and Uses

85At[210]
Halogen

Astatine (At): Electron Configuration, Properties and Uses

Electron configuration [Xe] 6s2 4f14 5d10 6p5 · group 17 · period 6 · Ar [210]

Astatine data

Atomic number
85
Relative atomic mass
[210]
Group
17
Period
6
Block
p
Category
Halogen
Electron configuration
[Xe] 6s2 4f14 5d10 6p5
Full configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p5
Electrons per shell
2, 8, 18, 32, 18, 7 (K L M N O P)
Valence electrons
7
Electronegativity (Pauling)
2.2
First ionisation energy
9.5 eV
Atomic radius (van der Waals)
202 pm
State at room temperature
Solid
Melting point
302 °C
Boiling point
no data
Density
7 g/cm³
Common oxidation states
+7, +5, +3, +1, −1
Discovered
1940

Source: PubChem (NIH, accessed 13 Nov 2026); atomic mass: IUPAC standard atomic weight.

Electron shell diagram

At

K 2 · L 8 · M 18 · N 32 · O 18 · P 7

Orbital diagram (outer electrons)

[Xe]↑↓6s2↑↓↑↓↑↓↑↓↑↓↑↓↑↓4f14↑↓↑↓↑↓↑↓↑↓5d10↑↓↑↓↑6p5

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About astatine

With atomic number 85, astatine (At) has 85 protons in its nucleus and 85 electrons as a neutral atom. It is a halogen in group 17, period 6, p-block. The element was discovered in 1940. Astatine is a solid at room temperature, melting at 302 °C.

Astatine electron configuration

The electron configuration of astatine is 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p5, or in short [Xe] 6s2 4f14 5d10 6p5. Its electrons occupy 6 shells: K = 2, L = 8, M = 18, N = 32, O = 18, P = 7. Astatine has 7 valence electrons in the P shell (6s2 6p5), which is why it sits in group 17.

Filling order: 1s2(2) → 2s2(4) → 2p6(10) → 3s2(12) → 3p6(18) → 4s2(20) → 3d10(30) → 4p6(36) → 5s2(38) → 4d10(48) → 5p6(54) → 6s2(56) → 4f14(70) → 5d10(80) → 6p5(85)

Uses of astatine

In industry and the laboratory, astatine turns up in many places, for example research on targeted alpha cancer therapy with At-211; one of the rarest naturally occurring elements in Earth’s crust.

Safety

Astatine is radioactive. Using, storing or transporting radioactive material requires a licence from the national regulator (BAPETEN in Indonesia). Always read the safety data sheet (SDS) before working with a chemical.

Other elements in group 17

Frequently asked questions

What is the electron configuration of astatine?

The electron configuration of astatine (At, atomic number 85) is 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p5, or [Xe] 6s2 4f14 5d10 6p5 in short. By shell: 2, 8, 18, 32, 18, 7.

How many valence electrons does astatine have?

Astatine has 7 valence electrons.

Which group and period is astatine in?

Astatine is in group 17, period 6, p-block.

What is the atomic mass of astatine?

Astatine has no stable isotope, so the mass number of its longest-lived isotope, [210], is given.

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