Calcium (Ca): Electron Configuration, Properties and Uses

20Ca40.078
Alkaline earth metal

Calcium (Ca): Electron Configuration, Properties and Uses

Electron configuration [Ar] 4s2 · group 2 · period 4 · Ar 40.078

Calcium data

Atomic number
20
Relative atomic mass
40.078
Group
2
Period
4
Block
s
Category
Alkaline earth metal
Electron configuration
[Ar] 4s2
Full configuration
1s2 2s2 2p6 3s2 3p6 4s2
Electrons per shell
2, 8, 8, 2 (K L M N)
Valence electrons
2
Electronegativity (Pauling)
1
First ionisation energy
6.113 eV
Atomic radius (van der Waals)
231 pm
State at room temperature
Solid
Melting point
842 °C
Boiling point
1484 °C
Density
1.54 g/cm³
Common oxidation states
+2
Discovered
ancient times

Source: PubChem (NIH, accessed 13 Nov 2026); atomic mass: IUPAC standard atomic weight.

Electron shell diagram

Ca

K 2 · L 8 · M 8 · N 2

Orbital diagram (outer electrons)

[Ar]↑↓4s2

Open in the electron configuration generator →

About calcium

Calcium, symbol Ca, is element number 20 in the periodic table. It is an alkaline earth metal in group 2, period 4, s-block. Calcium has been known and used since ancient times. Calcium is a solid at room temperature, melting at 842 °C and boiling at 1484 °C.

Calcium electron configuration

The electron configuration of calcium is 1s2 2s2 2p6 3s2 3p6 4s2, or in short [Ar] 4s2. Its electrons occupy 4 shells: K = 2, L = 8, M = 8, N = 2. Calcium has 2 valence electrons in the N shell (4s2), which is why it sits in group 2. When it forms cations, electrons leave the outermost subshell first: Ca2+ = [Ar] (like argon).

Filling order: 1s2(2) → 2s2(4) → 2p6(10) → 3s2(12) → 3p6(18) → 4s2(20)

Uses of calcium

Well-known applications of calcium include cement and lime, bones and teeth, calcium carbonate for paper and antacids, and as a reducing agent in metal production. For research and analysis you can browse calcium compounds in the AMI Scientific catalogue.

Safety

Calcium metal reacts with water to release hydrogen, though less violently than the alkali metals. Always read the safety data sheet (SDS) before working with a chemical.

Other elements in group 2

Frequently asked questions

What is the electron configuration of calcium?

The electron configuration of calcium (Ca, atomic number 20) is 1s2 2s2 2p6 3s2 3p6 4s2, or [Ar] 4s2 in short. By shell: 2, 8, 8, 2.

How many valence electrons does calcium have?

Calcium has 2 valence electrons.

Which group and period is calcium in?

Calcium is in group 2, period 4, s-block.

What is the atomic mass of calcium?

The relative atomic mass of calcium is 40.078. Use it to calculate molar mass with the molar mass calculator.

Need calcium compounds for your lab?

AMI Scientific is one of the official TCI distributors in Indonesia. Reagents with lot CoA & SDS, formal quotations and tax invoices for universities and laboratories.

Other formulas & calculators: molarity, mole, molality, normality, dilution, titration, pH, buffer, molar mass, ppm, mole fraction, mass percent, periodic table, chemical MSDS.