TCI
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Description
TCI C0858 12-Crown 4-Ether (CAS 294-93-9) is the smallest of the commonly used crown ether series, featuring a macrocyclic cavity lined with four oxygen donor atoms. Its cavity dimensions give it a favorable fit for small cations, particularly lithium, which makes it valuable for ion-recognition studies and ion-selective electrode research. As a phase-transfer catalyst, it complexes the cation and leaves the counter-anion more reactive, accelerating substitution and elimination reactions in non-polar media. Supplied in 1mL and 5mL laboratory volumes, it should be stored cool, dry, and tightly sealed, and handled with appropriate personal protective equipment.
Scientific References
- Junk, (2001). STRUCTURAL ASPECTS OF OXONIUM ION/CROWN ETHER COMPLEXES. Reviews in Inorganic Chemistry doi:10.1515/revic.2001.21.1-2.93
- Liu (2007). Ether and crown ether-containing cationic 99mTc complexes useful as radiopharmaceuticals for heart imaging. Dalton Transactions doi:10.1039/b618406e
- Rogers et al. (1992). Crown ether complexes of lead(II) nitrate. Crystal structures of the 12-crown-4, 15-crown-5, benzo-15-crown-5 and 18-crown-6 complexes. Inorganica Chimica Acta doi:10.1016/s0020-1693(00)80755-0
References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.
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