15-Crown 5-Ether TCI C0859

Chemical Identity

Other names: 1,4,7,10,13-Pentaoxacyclopentadecane
CAS No.: 33100-27-5
Formula: C10H20O5
Molecular weight: 220.27 g/mol
Purity: >97.0%(GC)

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: 1,4,7,10,13-pentaoxacyclopentadecane
SMILES: C1COCCOCCOCCOCCO1
InChIKey: VFTFKUDGYRBSAL-UHFFFAOYSA-N
MDL: MDL00005110
PubChem: CID 36336

Rp 1.618.050,00

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Volume 5mL 25mL

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TCI C0859 15-Crown 5-Ether (CAS 33100-27-5) is a macrocyclic polyether whose five oxygen donor atoms coordinate alkali metal cations, with a cavity size commonly associated with sodium ion binding. It is widely used as a phase-transfer catalyst, solubilizing inorganic salts into organic media and enhancing the reactivity of the accompanying anion. Researchers also employ it as an ionophore in ion-selective membrane formulations and as a host molecule in supramolecular host–guest studies. Offered in 5mL and 25mL packs, the liquid reagent should be kept tightly closed, cool, and dry, and handled with suitable protective equipment in a fume hood.

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Kijima et al. (2003). Enzymatic Hydrolysis of 4′-(1-Chloro-2-Acetoxyethyl)-Benzo-15-Crown-5-Ether and 4′-Acetoxyethyl-Benzo-15-Crown-5-Ether; a Facile Synthesis of the Optically Active Chlorohydrin Analogue Incorporating Crown Ether. Journal of Chemical Research doi:10.3184/030823403103174362
GROMOV et al. (1996). ChemInform Abstract: Crown Ether Styryl Dyes. Part 14. Synthesis, Luminescence and Complex Formation of trans‐Isomers of Chromogenic 15‐Crown‐5‐ether.. ChemInform doi:10.1002/chin.199608202
Shubert et al. (2009). Jet-Cooled Electronic and Vibrational Spectroscopy of Crown Ethers: Benzo-15-Crown-5 Ether and 4′-Amino-Benzo-15-Crown-5 Ether. The Journal of Physical Chemistry A doi:10.1021/jp904231d

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.