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TCI

CAS 1334529-08-6

6,7-Dihydro-2-(2,4,6-trimethylphenyl)-5H-pyrrolo[2,1-c]-1,2,4-triazolium Perchlorate TCI D3982

6,7-Dihydro-2-(2,4,6-trimethylphenyl)-5H-pyrrolo[2,1-c]-1,2,4-triazolium Perchlorate TCI D3982

Chemical Identity

Other names
6,7-Dihydro-2-mesityl-5H-pyrrolo[2,1-c]-1,2,4-triazolium Perchlorate
CAS No.
1334529-08-6
PubChem
CID 49758092·SID 125307469
Formula
C14H18ClN3O4
Molecular weight
327.77 g/mol
Purity
>98.0%(HPLC)
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
2-(2,4,6-trimethylphenyl)-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-4-ium perchlorate
SMILES
CC1=CC(=C(C(=C1)C)N2C=[N+]3CCCC3=N2)C.[O-]Cl(=O)(=O)=O
InChIKey
LWDOZOIYYGPFSI-UHFFFAOYSA-M
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6,7-Dihydro-2-(2,4,6-trimethylphenyl)-5H-pyrrolo[2,1-c]-1,2,4-triazolium Perchlorate is a specialized chemical compound used in laboratory settings for catalytic and inorganic chemistry applications. This compound plays a crucial role in facilitating chemical reactions by acting as a carbon-donor ligand, enabling efficient electron transfer and activation. Its unique molecular structure allows it to interact effectively with metal ions under controlled conditions, making it a valuable tool in synthetic chemistry. The compound is particularly useful in scenarios where precise control over reaction pathways is required.

The compound is preferred due to its stability under specific conditions and its ability to enhance reaction efficiency without altering the fundamental properties of the substrates. Its molecular structure provides a high degree of reactivity, which is essential in catalytic processes. Additionally, its chemical stability ensures that it remains effective over extended periods when stored properly. The compound’s sensitivity to moisture and air necessitates careful handling, but this also highlights its reactivity and potential for use in advanced chemical applications.

In Indonesian laboratories, this compound is commonly used in research related to catalysis and organic synthesis. It is particularly favored for its role in accelerating chemical reactions while maintaining the integrity of the reaction environment. Its availability in solid form simplifies handling and integration into various experimental setups, making it a practical choice for both academic and industrial research. Its application in chemical research underscores its importance in advancing scientific understanding and innovation.

TCI brochures (PDF)

  • Catalytic Reaction Optimization: This compound is ideal for catalytic processes where precise control over electron transfer and metal ion interaction is essential.
  • Organic Synthesis Research: It supports the development of new synthetic pathways by facilitating efficient ligand-metal interactions in organic reactions.
  • Inorganic Chemistry Studies: Its ability to interact with metal ions makes it a key component in inorganic chemistry experiments involving coordination complexes.
  • Electronic Activation Studies: The compound is used in experiments that require the activation of electron transfer processes in chemical reactions.
  • Advanced Material Development: It plays a role in the synthesis of new materials by enabling controlled chemical reactions that lead to novel compound formations.

From the TCI brochure

  • Annulation of alpha'-hydroxyenones and enamines

Brand TCI
CAS number 1334529-08-6
Molecular formula —
Purity —
Category Chemistry > Catalysis and Inorganic Chemistry > Carbon-Donor Ligands [Catalysis]
Pack sizes —
Physical form Solid
Storage Keep in a dry, cool place away from moisture and air exposure

Data from the TCI brochure

Catalyst loading10 mol% (K2CO3 (15 mol%), oxidant (1.2 eq.), Toluene, 40 °C)

Source: TCI brochure RR060 (2025-01-16)

This compound should be stored in a dry, cool environment to prevent degradation due to moisture and air exposure. It is recommended to use airtight containers to minimize contact with atmospheric humidity. Due to its sensitivity, it should be handled in a controlled laboratory setting with proper ventilation. Avoid direct exposure to light and heat to maintain its chemical stability. Always use appropriate personal protective equipment when handling this material to ensure safety during experiments. Proper storage and handling are essential to preserve its effectiveness in catalytic and synthetic applications.

References cited in the TCI brochure

  1. Benedikt Wanner. Enantioselective Synthesis of Dihydropyridinones via NHC-Catalyzed Aza-Claisen Reaction Organic Letters, 2011. doi:10.1021/ol202272t