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CAS 808-57-1

2,3,6,7,10,11-Hexamethoxytriphenylene TCI H0898

2,3,6,7,10,11-Hexamethoxytriphenylene TCI H0898
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TCI H0898 2,3,6,7,10,11-Hexamethoxytriphenylene is a polycyclic aromatic compound built around a flat triphenylene core surrounded symmetrically by six methoxy groups at the peripheral positions. The compound occupies an important place in materials chemistry, since the triphenylene core is one of the most classical discotic aromatic frameworks studied since the early development of columnar liquid crystals. In the laboratory, this material serves as a model molecule, a precursor for functional materials, and at the same time a starting material for preparing hydroxy and long-chain alkoxy derivatives that form the backbone of modern organic materials research.

The property that makes it a frequent choice is the high electron density of the aromatic core, granted by six electron-donating groups, combined with a planar geometry that promotes π–π stacking between molecules. This columnar molecular arrangement is precisely what gives rise to one-dimensional charge transport pathways, a property sought after in organic semiconductors and optoelectronic devices. In addition, the methoxy groups can be demethylated into six hydroxyl groups, yielding hexahydroxytriphenylene, which has now become a popular ligand for covalent organic frameworks as well as related framework materials.

In Indonesian laboratories, this compound is typically used in university and institutional research groups working on organic materials, organic synthesis, and supramolecular chemistry. It is normally ordered in small research quantities for exploratory synthesis, derivatisation studies, and the preparation of discotic mesogens or framework precursors. Research teams working on organic electronics, self-assembly, and porous materials generally keep it as a specialised building block rather than as a bulk consumable, ordering it per project as the synthetic route requires.

  • Discotic liquid crystal research: the planar, symmetric triphenylene core is the classical scaffold for columnar mesophases, making this compound a reliable reference structure for mesomorphic studies.
  • Organic semiconductor development: π–π stacking between flat, electron-rich cores creates one-dimensional charge transport pathways that researchers exploit when designing organic electronic and optoelectronic materials.
  • Precursor to hexahydroxytriphenylene: the six methoxy groups can be demethylated to hydroxyls, giving direct access to a widely used ligand for framework material synthesis.
  • Covalent organic framework synthesis: as the upstream source of the hexahydroxy ligand, it supports research groups building porous covalent and related framework materials from triphenylene nodes.
  • Synthesis of long-chain alkoxy derivatives: the methoxy positions provide defined handles for installing extended alkoxy chains that underpin much of modern organic materials research.

Brand TCI
CAS number 808-57-1
Molecular formula
Purity
Category Chemistry > Building Blocks > Non-Heterocyclic Building Blocks
Pack sizes available in research-scale catalogue pack sizes as supplied by TCI
Physical form
Storage store according to the manufacturer's instructions stated on the product label and safety data sheet
  • Product code: H0898

Store the compound in its original tightly closed container, kept in a cool, dry, well-ventilated place away from direct sunlight, moisture, and incompatible materials, following the conditions stated on the manufacturer's label and safety data sheet. Amber glass or the supplied original packaging is suitable for keeping the solid protected from light. Handle in a fume hood using a laboratory coat, safety glasses, and chemical-resistant gloves, and avoid generating or inhaling dust when weighing. Close the container promptly after use, label all transfers clearly, and consult the safety data sheet before handling or disposal.