RuCl2[(R)-xylbinap][(R)-daipen] TCI R0133

Chemical Identity

CAS No.: 220114-32-9
PubChem: CID 56837972·SID 253659927
Formula: C71H74Cl2N2O2P2Ru
Molecular weight: 1221.3 g/mol

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: [1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;(2R)-1,1-bis(4-methoxyphenyl)-3-methylbutane-1,2-diamine;ruthenium(2+);dichloride
SMILES: CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.CC(C)[C@H](C(C1=CC=C(C=C1)OC)(C2=CC=C(C=C2)OC)N)N.[Cl-].[Cl-].[Ru+2]
InChIKey: UTQCNMRDWASSEC-OEGAAENXSA-L

Rp 1.485.750,00

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Berat 200mg 1g

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TCI R0133 220114-32-9 RuCl2[(R)-xylbinap][(R)-daipen] is a chiral catalyst used in asymmetric synthesis, playing a crucial role in laboratories that require precise control over stereochemistry. This compound is specifically designed to facilitate reactions that produce compounds with defined spatial structures. Its application is essential in organic chemistry research where the stereochemical outcome of a reaction is critical. The compound's unique structure allows it to act as a chiral ligand, enhancing the selectivity of chemical transformations.

The compound's chiral nature and complex structure make it a preferred choice for researchers aiming to achieve high stereoselectivity and efficiency in chemical reactions. Its ability to direct the formation of specific enantiomers is a key factor in its widespread use. The combination of ruthenium metal and chiral ligands provides a highly effective platform for catalytic processes. This makes it particularly valuable in the development of new pharmaceuticals and fine chemicals, where precise stereochemical control is required.

In Indonesian laboratories, TCI R0133 220114-32-9 is widely used in scientific research and industrial chemical development. It is a key component in experiments related to asymmetric synthesis and the creation of new chemical products. Many research institutions and universities in Indonesia rely on this compound for its reliability and effectiveness in achieving desired chemical outcomes.

TCI brochures (PDF)

Ruthenium Complex Catalysts for Asymmetric Hydrogenation of Ketons 2024-12-16 · p. 2
Hydrogenation Catalysts 2025-11-10 · p. 8

Related TCI products

Asymmetric Synthesis for producing compounds with specific spatial structures due to its chiral catalytic properties.
High Stereoselectivity Reactions requiring precise control over enantiomer formation through its chiral ligand structure.
Pharmaceutical Catalyst Development for creating chiral drugs with enhanced efficacy and reduced side effects.
Organic Chemistry Research for exploring new reaction mechanisms and improving synthetic pathways.
Industrial Chemical Innovation for developing new products with controlled stereochemistry in manufacturing processes.

Brand	TCI
CAS number	220114-32-9
Molecular formula	—
Purity	—
Category	Chemistry > Asymmetric Synthesis > Chiral Catalysts, Chiral Ligands, Chiral Reagents
Pack sizes	—
Physical form	—
Storage	Store in a cool, dry place away from light and moisture

This compound should be stored in a cool, dry environment, away from direct light and moisture to maintain its chemical integrity. It is recommended to use airtight containers made of materials that are chemically inert, such as glass or polyethylene, to prevent any reaction with the environment. Proper labeling of containers is essential for safe handling and to avoid accidental exposure. In laboratory settings, it is important to use appropriate personal protective equipment, including gloves and safety goggles, when handling this material. Regular monitoring of storage conditions ensures that the compound remains stable and effective for its intended applications.

References cited in the TCI brochure

Takeshi Ohkuma. Asymmetric Hydrogenation of Alkenyl, Cyclopropyl, and Aryl Ketones. RuCl2(xylbinap)(1,2-diamine) as a Precatalyst Exhibiting a Wide Scope Journal of the American Chemical Society, 1998. doi:10.1021/ja983257u
Takeshi Ohkuma. Selective Hydrogenation of Benzophenones to Benzhydrols. Asymmetric Synthesis of Unsymmetrical Diarylmethanols Organic Letters, 2000. doi:10.1021/ol9904139