RuCl2[(R)-xylbinap][(R,R)-dpen] TCI R0135

Chemical Identity

CAS No.: 220114-38-5
PubChem: CID 91972078·SID 253659929
Formula: C66H64Cl2N2P2Ru
Molecular weight: 1119.1 g/mol

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: [1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;(1R,2R)-1,2-diphenylethane-1,2-diamine;ruthenium(2+);dichloride
SMILES: CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.C1=CC=C(C=C1)[C@H]([C@@H](C2=CC=CC=C2)N)N.[Cl-].[Cl-].[Ru+2]
InChIKey: HYMSONXJNGZZBM-ODQAEMFESA-L

Rp 1.485.750,00

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Berat 200mg 1g

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TCI R0135 220114-38-5 RuCl2[(R)-xylbinap][(R,R)-dpen] is a chiral reagent used in asymmetric synthesis, playing a crucial role in chemical laboratories. It is specifically designed to facilitate reactions that require precise control over stereochemistry, making it essential for the synthesis of complex organic molecules. This compound is widely applied in research settings where the creation of enantiomerically pure compounds is necessary, such as in pharmaceutical development and advanced organic chemistry. Its unique structure allows it to interact selectively with substrates, enhancing the efficiency of chemical transformations.

The key properties that make this reagent a preferred choice include its high catalytic activity and stability under controlled laboratory conditions. Its ability to maintain the desired stereochemistry throughout the reaction process ensures consistent and reproducible results. Additionally, the compound’s complex composition enables it to act as a chiral catalyst, promoting the formation of specific stereoisomers with minimal side reactions. These characteristics make it a reliable tool for researchers aiming to achieve high selectivity and yield in their experiments.

In Indonesian laboratories, this reagent is highly relevant for research in organic chemistry, pharmaceutical sciences, and biochemistry. It is commonly used in academic and industrial settings where the synthesis of chiral compounds is required. Its application supports various research projects, particularly those focused on drug development and the study of complex organic molecules. The availability of this reagent through AMI Scientific ensures that Indonesian researchers have access to high-quality materials for their experiments.

TCI brochures (PDF)

Ruthenium Complex Catalysts for Asymmetric Hydrogenation of Ketons 2024-12-16 · p. 2
Hydrogenation Catalysts 2025-11-10 · p. 8

Related TCI products

Asymmetric Synthesis: This reagent is ideal for asymmetric synthesis due to its ability to control stereochemistry, enabling the selective formation of enantiomers in complex organic molecules.
Pharmaceutical Research: It is widely used in drug development to synthesize chiral compounds with high enantiomeric purity, which is essential for pharmaceutical applications.
Organic Chemistry Experiments: The compound's catalytic properties make it a valuable tool for conducting precise and efficient organic reactions in both academic and industrial laboratories.
Biochemical Studies: It supports research in biochemistry by facilitating the synthesis of chiral compounds used in enzyme studies and receptor interactions.
Industrial Catalysis: Its stability and reactivity make it suitable for large-scale chemical processes requiring controlled stereochemical outcomes in industrial settings.

Brand	TCI
CAS number	220114-38-5
Molecular formula	—
Purity	—
Category	Chemistry > Asymmetric Synthesis > Chiral Catalysts, Chiral Ligands, Chiral Reagents
Pack sizes	Available in various quantities as per standard laboratory supply
Physical form	Solid or powder, depending on the specific formulation
Storage	Store in a cool, dry place away from light and moisture

This reagent should be stored in a cool, dry environment, away from direct sunlight and moisture to maintain its stability and effectiveness. It is recommended to use airtight containers to prevent exposure to air and humidity, which could affect its performance. Due to its chemical nature, it should be handled with appropriate personal protective equipment, such as gloves and safety goggles, to ensure laboratory safety. The compound is generally non-hazardous under normal conditions but should be stored in a well-ventilated area. Proper labeling of containers is essential to prevent accidental use. Regular monitoring of storage conditions is advised to ensure the reagent remains in optimal condition for use in research applications.

References cited in the TCI brochure

Takeshi Ohkuma. Asymmetric Hydrogenation of Alkenyl, Cyclopropyl, and Aryl Ketones. RuCl2(xylbinap)(1,2-diamine) as a Precatalyst Exhibiting a Wide Scope Journal of the American Chemical Society, 1998. doi:10.1021/ja983257u
Takaji Matsumoto. Diastereoselective synthesis of a key intermediate for the preparation of tricyclic β-lactam antibiotics Tetrahedron Letters, 1999. doi:10.1016/s0040-4039(99)00929-6