(6,6)Carbon Nanobelt as a Synthetic Tool for Cycloiptycenes and Red Light Emitter
(6,6)Carbon Nanobelt Bis(tetrahydrofuran) Adduct (I1078) is a new carbon material first synthesized in 2017 after more than 60 years of challenges.¹) It has a rigid belt structure of 12 fully fused benzene rings, is a partial structure of armchair-type carbon nanotube (CNT), and has properties similar to (6,6)CNT. The product shows red light emission with λem = 630 nm (λex = 500 nm in CH2Cl2). In synthesis, (6,6)carbon nanobelt reacts as a diene in the Diels–Alder reaction with arynes and alkynes such as diphenylacetylene (D0871), with the reaction taking place at the six central benzene rings. This method allows a variety of cycloiptycenes to be synthesized easily in one step.
Related products
- TCI I1078 2245104-25-8 (6,6)Carbon Nanobelt Bis(tetrahydrofuran) Adduct
- TCI C1961 191-07-1 Coronene (purified by sublimation)
- TCI C2449 1092522-75-2 [12]Cycloparaphenylene
- TCI C2572 5821-51-2 Corannulene
- TCI C2931 96100-94-6 [5]Cycloparaphenylene
- TCI C3386 156980-13-1 [6]Cycloparaphenylene
- TCI P1629 198-55-0 Perylene (purified by sublimation)
- TCI S0888 151253-59-7 Sumanene
Source
- TCI Product Highlights: www.tcichemicals.com/ID/en/product/tci-topics/ProductHighlights_20210517
- TCI product page I1078: tcichemicals.com/ID/en/p/I1078
- TCI brochure FF076: Next-Generation Carbon Material with Infinite Potential: (6,6)Carbon Nanobelt
For research and laboratory use only, not for human consumption.
