Francium (Fr): Electron Configuration, Properties and Uses

87Fr[223]
Alkali metal

Francium (Fr): Electron Configuration, Properties and Uses

Electron configuration [Rn] 7s1 · group 1 · period 7 · Ar [223]

Francium data

Atomic number
87
Relative atomic mass
[223]
Group
1
Period
7
Block
s
Category
Alkali metal
Electron configuration
[Rn] 7s1
Full configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s1
Electrons per shell
2, 8, 18, 32, 18, 8, 1 (K L M N O P Q)
Valence electrons
1
Electronegativity (Pauling)
0.7
First ionisation energy
3.9 eV
Atomic radius (van der Waals)
348 pm
State at room temperature
Solid
Melting point
26.9 °C
Boiling point
no data
Density
no data
Common oxidation states
+1
Discovered
1939

Source: PubChem (NIH, accessed 13 Nov 2026); atomic mass: IUPAC standard atomic weight.

Electron shell diagram

Fr

K 2 · L 8 · M 18 · N 32 · O 18 · P 8 · Q 1

Orbital diagram (outer electrons)

[Rn]↑7s1

Open in the electron configuration generator →

About francium

Francium is a chemical element with the symbol Fr and atomic number 87. It is an alkali metal in group 1, period 7, s-block. The element was discovered in 1939. Francium is a solid at room temperature, melting at 26.9 °C.

Francium electron configuration

The electron configuration of francium is 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s1, or in short [Rn] 7s1. Its electrons occupy 7 shells: K = 2, L = 8, M = 18, N = 32, O = 18, P = 8, Q = 1. Francium has 1 valence electron in the Q shell (7s1), which is why it sits in group 1. When it forms cations, electrons leave the outermost subshell first: Fr+ = [Rn] (like radon).

Filling order: 1s2(2) → 2s2(4) → 2p6(10) → 3s2(12) → 3p6(18) → 4s2(20) → 3d10(30) → 4p6(36) → 5s2(38) → 4d10(48) → 5p6(54) → 6s2(56) → 4f14(70) → 5d10(80) → 6p6(86) → 7s1(87)

Uses of francium

Francium is used for research only; francium is so rare and short-lived that it is studied only in atomic-physics experiments.

Safety

Francium is radioactive. Using, storing or transporting radioactive material requires a licence from the national regulator (BAPETEN in Indonesia). Always read the safety data sheet (SDS) before working with a chemical.

Other elements in group 1

Frequently asked questions

What is the electron configuration of francium?

The electron configuration of francium (Fr, atomic number 87) is 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s1, or [Rn] 7s1 in short. By shell: 2, 8, 18, 32, 18, 8, 1.

How many valence electrons does francium have?

Francium has 1 valence electron.

Which group and period is francium in?

Francium is in group 1, period 7, s-block.

What is the atomic mass of francium?

Francium has no stable isotope, so the mass number of its longest-lived isotope, [223], is given.

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