Lithium (Li): Electron Configuration, Properties and Uses

3Li6.94
Alkali metal

Lithium (Li): Electron Configuration, Properties and Uses

Electron configuration [He] 2s1 · group 1 · period 2 · Ar 6.94

Lithium data

Atomic number
3
Relative atomic mass
6.94
Group
1
Period
2
Block
s
Category
Alkali metal
Electron configuration
[He] 2s1
Full configuration
1s2 2s1
Electrons per shell
2, 1 (K L)
Valence electrons
1
Electronegativity (Pauling)
0.98
First ionisation energy
5.392 eV
Atomic radius (van der Waals)
182 pm
State at room temperature
Solid
Melting point
180 °C
Boiling point
1342 °C
Density
0.534 g/cm³
Common oxidation states
+1
Discovered
1817

Source: PubChem (NIH, accessed 13 Nov 2026); atomic mass: IUPAC standard atomic weight.

Electron shell diagram

Li

K 2 · L 1

Orbital diagram (outer electrons)

[He]↑2s1

Open in the electron configuration generator →

About lithium

Lithium is a chemical element with the symbol Li and atomic number 3. It is an alkali metal in group 1, period 2, s-block. The element was discovered in 1817. Lithium is a solid at room temperature, melting at 180 °C and boiling at 1342 °C. Its density of 0.534 g/cm³ is lower than water, so the metal floats.

Lithium electron configuration

The electron configuration of lithium is 1s2 2s1, or in short [He] 2s1. Its electrons occupy 2 shells: K = 2, L = 1. Lithium has 1 valence electron in the L shell (2s1), which is why it sits in group 1. When it forms cations, electrons leave the outermost subshell first: Li+ = [He] (like helium).

Filling order: 1s2(2) → 2s1(3)

Uses of lithium

The main uses of lithium include lithium-ion batteries for phones and electric vehicles, lubricating greases, heat-resistant glass and ceramics, and mood-stabilising medicine (lithium carbonate). For research and analysis you can browse lithium compounds in the AMI Scientific catalogue.

Safety

Lithium metal reacts with water and moisture, so it is stored under mineral oil or argon. Always read the safety data sheet (SDS) before working with a chemical.

Other elements in group 1

Frequently asked questions

What is the electron configuration of lithium?

The electron configuration of lithium (Li, atomic number 3) is 1s2 2s1, or [He] 2s1 in short. By shell: 2, 1.

How many valence electrons does lithium have?

Lithium has 1 valence electron.

Which group and period is lithium in?

Lithium is in group 1, period 2, s-block.

What is the atomic mass of lithium?

The relative atomic mass of lithium is 6.94. Use it to calculate molar mass with the molar mass calculator.

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