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CAS 129648-07-3

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane TCI B5985

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane TCI B5985

Chemical Identity

Other names
Me-BPE · (R,R)-Me-BPE · (R,R)-Me-BPE · 1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane
CAS No.
129648-07-3
PubChem
CID 2734555·SID 468590824
Formula
C14H28P2
Molecular weight
258.33 g/mol
Purity
>95.0%(GC)
Reference databases
ChemSpider·ECHA
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane
SMILES
CC1CCC(P1CCP2C(CCC2C)C)C
InChIKey
IRCDUOCGSIGEAI-AAVRWANBSA-N
MDL
MDL01073770
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1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane is a chiral bidentate bisphospholane ligand widely used in asymmetric hydrogenation reactions with transition metal catalysts. It forms highly effective chiral complexes with rhodium and ruthenium, enabling the enantioselective reduction of prochiral olefins, ketones, and imines. This ligand is a reliable choice for pharmaceutical and fine chemical synthesis requiring high optical purity.

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