[1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) Dichloride TCI B6199

Chemical Identity

Other names: [1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene](dichloro)(3-chloropyridine-kappaN)palladium · Organ's Catalyst
CAS No.: 905459-27-0
PubChem: CID 16218181
Formula: C32H40Cl3N3Pd
Molecular weight: 679.46 g/mol
Purity: >95.0%(T)

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: 1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazole;3-chloropyridine;dichloropalladium
SMILES: CC(C)C1=C(C(=CC=C1)C(C)C)N2CN(C=C2)C3=C(C=CC=C3C(C)C)C(C)C.C1=CC(=CN=C1)Cl.Cl[Pd]Cl
InChIKey: BLDKGTGQENJFON-UHFFFAOYSA-L
MDL: MDL08457656

Rp 3.922.800,00

~~Rp 2.758.350,00~~ Rp 3.922.800,00

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TCI B6199 [1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) Dichloride is a palladium(II) NHC catalyst specifically developed for C–H bond activation reactions. This catalyst enables direct functionalization of carbon–hydrogen bonds, streamlining synthetic pathways in organic chemistry. It is widely employed in C–H arylation, alkylation, and alkenylation reactions for the synthesis of pharmaceuticals, agrochemicals, and advanced functional materials.

Advantages (TCI brochure)

Crystalline solid, stable against air and moisture
Efficiently catalyzes various types of C-C and C-N bond forming reactions
Easy to remove palladium after reaction

TCI brochures (PDF)

Palladium Catalyst with Both Ease-of-Handling and High Reactivity 2025-01-06 · p. 1
Useful Palladacycle Catalysts 2025-04-17 · p. 1
N-Heterocyclic Carbene (NHC) Ligands and Metal Complexes 2026-02-10 · p. 2
C-H Bond Activation Reaction 2025-06-20 · p. 4
Transition Metal Catalysts 2026-04-10 · p. 14
Suzuki-Miyaura Cross Coupling Reaction 2025-12-01 · p. 23

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From the TCI brochure

C-C bond forming reaction of an aryl chloride with an arylboronic acid: B6199 (1mol%), KOtBu, iPrOH, rt, 2h
C-N bond forming reaction of an aryl chloride with an aniline derivative: B6199 (2mol%), KOtBu, DME, rt, 24h