Bismuth(III) Fluoride (CAS 7787-61-3) is a main-group inorganic solid that serves as a convenient source of both bismuth(III) and fluoride in laboratory work. It is widely used as a precursor for bismuth-based ceramics and oxyfluoride phases, and it features in studies of fluoride-ion conducting materials and solid electrolytes. Its low water solubility makes gravimetric handling straightforward in solid-state preparations. TCI product B6338 is supplied in 25 g and 100 g packs; handle the powder in a fume hood, keep it tightly closed away from moisture and acids, and refer to the manufacturer's Safety Data Sheet.
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- Sawant et al. (1993). A study on the fluoride complexes of plutonium(III), samarium(III) and bismuth(III) using fluoride ion-selective potentiometry. Journal of Radioanalytical and Nuclear Chemistry Articles doi:10.1007/bf02134591
- Konishi et al. (2020). Effect of anion acceptor added to the electrolyte on the electrochemical performance of bismuth(III) fluoride in a fluoride shuttle battery. Chemical Physics Letters doi:10.1016/j.cplett.2020.137785
- Konishi et al. (2020). Reversible Electrochemical Reaction of a Fluoride Shuttle Battery with a Bismuth(III) Fluoride Electrode and Electrolyte Containing Triphenylboroxine as an Anion Acceptor. ChemistrySelect doi:10.1002/slct.202001163
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