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Description
Bismuth(III) Bromide (CAS 7787-58-8) is a moisture-sensitive main-group halide that is widely valued as a mild, relatively low-toxicity Lewis acid catalyst. It promotes carbonyl activation, acetal formation and deprotection, allylation and a range of multicomponent condensations, often at low catalyst loading. In materials chemistry it also serves as a bismuth and bromide source for BiOBr photocatalysts and lead-free bismuth-based semiconductors. TCI product B6339 comes in 5 g and 25 g packs; weigh it quickly under dry conditions, store it tightly sealed in a desiccator, and follow the manufacturer's Safety Data Sheet.
Scientific References
Soltanzadeh et al. (2009). Syntheses and characterization of a new nano-structured bismuth(III) bromide coordination polymer; new precursor for preparation of bismuth(III) bromide and bismuth(III) oxide nanostructures. Journal of Coordination Chemistrydoi:10.1080/00958970902951629
SALVATORE et al. (1992). ChemInform Abstract: Bismuth(III) Bromide Complexes: On the Formation of Species Higher Than BiBr3‐ 6 in Concentrated Bromide Solutions.. ChemInformdoi:10.1002/chin.199207011
Soltanzadeh et al. (2009). Metal–organic supramolecular assemblies generated from bismuth(III) bromide and polyimine ligands. Polyhedrondoi:10.1016/j.poly.2008.12.048
References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.
