TCI C0590 Benzyl Carbamate (CAS 621-84-1) is a crystalline carbamate widely used as a Cbz-protected nitrogen source. It serves as a nitrogen nucleophile in multicomponent reactions, additions to N-acyliminium intermediates, and catalytic amination chemistry, delivering products that are already protected. The benzyloxycarbonyl group can later be removed cleanly by hydrogenolysis, which keeps synthetic sequences short. AMI Scientific provides this TCI building block in 25 g and 250 g packs.
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- Tsujimoto et al. (2002). Efficient Detachment of N‐Benzyl Carbamate Group.. ChemInform doi:10.1002/chin.200245057
- Paromov (2023). Condensation of Benzyl Carbamate with Glyoxal in Polar Protic and Aprotic Solvents. Molecules doi:10.3390/molecules28227648
- Murai et al. (2002). Efficient Detachment ofN-Benzyl Carbamate Group. Synlett doi:10.1055/s-2002-32986
References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.
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