tert-Butyl Carbazate TCI C0933

Chemical Identity

Other names: Boc-hydrazine · tert-Butoxycarbonylhydrazine · Carbazic Acid tert-Butyl Ester
CAS No.: 870-46-2
PubChem: CID 70091·SID 125308839
Formula: C5H12N2O2
Molecular weight: 132.16 g/mol
Purity: >97.0%(GC)(T)
Reference databases: ChemSpider·ECHA

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: tert-butyl N-aminocarbamate
SMILES: CC(C)(C)OC(=O)NN
InChIKey: DKACXUFSLUYRFU-UHFFFAOYSA-N
MDL: MDL00007593

Rp 2.068.500,00

~~Rp 1.461.600,00~~ Rp 2.068.500,00

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tert-Butyl carbazate, widely known as Boc-hydrazine, is a mono-protected hydrazine derivative that offers far safer and more selective handling than free hydrazine. Its free terminal nitrogen reacts readily with aldehydes, ketones, and activated carboxylic acid derivatives, while the Boc group can be removed under standard acidic deprotection conditions. It is routinely used in peptide chemistry, hydrazide synthesis, bioconjugation linker preparation, and the construction of nitrogen heterocycles. TCI offers this solid reagent in 25 g and 250 g packs; store it tightly sealed in a cool, dry place and handle it in a fume hood with appropriate protective equipment.

TCI brochures (PDF)

Protecting Agents 2025-03-25 · p. 9
Amino Acids and Peptide Synthesis Reagents 2025-08-14 · p. 40

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Aitken et al. (2022). tert-Butyl Carbazate (N-Boc-Hydrazine). Molbank doi:10.3390/m1482
Ioannidou et al. (2009). tert-Butyl 3-(4-Cyano-5-phenylisothiazol-3-yl)carbazate. Molbank doi:10.3390/m628
Barluenga et al. (2007). Palladium‐Catalyzed Cross‐Coupling Between Vinyl Halides and tert‐Butyl Carbazate: First General Synthesis of the Unusual N‐Boc‐N‐alkenylhydrazines.. ChemInform doi:10.1002/chin.200718049

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.