• TCI D4887 676525-77-2 (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
  • (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate (CAS 676525-77-2) - TCI D4887 - AMI Scientific
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TCI

CAS 676525-77-2

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate TCI D4887

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate TCI D4887

Chemical Identity

Other names
Ir[(ppy)2(dtbbpy)]PF6 · [4,4-Di-tert-butyl-2,2'-bipyridine-kappaN1,kappaN1']bis[2-(2-pyridinyl-kappaN)phenyl-kappaC]iridium(III) Hexafluorophosphate
CAS No.
676525-77-2
PubChem
CID 60146995·SID 253661441
Formula
C40H40F6IrN4P
Molecular weight
913.97 g/mol
Purity
>85.0%(HPLC)(qNMR)
Storage
0-10°C
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
4-tert-butyl-2-(4-tert-butyl-2-pyridinyl)pyridine;iridium(3+);bis(2-phenylpyridine);hexafluorophosphate
SMILES
CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C.C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=C([C-]=C1)C2=CC=CC=N2.F[P-](F)(F)(F)(F)F.[Ir+3]
InChIKey
VCIVELSSYHAWGC-UHFFFAOYSA-N
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This compound, 4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate, is a metal complex used extensively in catalytic reactions and organic synthesis. As a transition metal complex, it plays a critical role in laboratory settings by facilitating chemical reactions that require electronic activation or interaction with reactive substrates. Its unique structure and chemical properties make it a valuable tool for researchers working in catalysis and inorganic chemistry. This material is particularly useful in environments where high stability and reactivity are required.

The compound is preferred due to its high chemical stability and efficiency as a catalyst under specific reaction conditions. Its complex structure allows for specific interactions with substrates, enhancing the overall efficiency of chemical reactions. Additionally, it exhibits relatively low toxicity compared to other metal catalysts, making it a safer option for laboratory use. These properties contribute to its widespread application in both academic and industrial research settings.

In Indonesian laboratories, this material is highly relevant for organic chemistry and catalysis research. It is commonly used in academic institutions and research centers to accelerate chemical reactions without significant degradation. Its reliability and performance make it a go-to choice for scientists working on advanced synthetic processes and catalytic systems.

TCI brochures (PDF)

Related TCI products

  • Organic synthesis reactions benefit from this compound's ability to activate substrates and enhance reaction efficiency.
  • Catalytic processes in polymerization require a stable and efficient catalyst, which this material provides.
  • Transition metal-based research utilizes its unique structure for studying coordination chemistry and reactivity.
  • Electrochemical studies take advantage of its stability and reactivity in controlled environments.
  • Analytical chemistry applications benefit from its specificity in interacting with reactive substrates.

From the TCI brochure

  • Visible light photoredox catalyst (cat.) in the synthesis, under blue light (34W), r.t.

Brand TCI
CAS number 676525-77-2
Molecular formula —
Purity —
Category Chemistry > Catalysis and Inorganic Chemistry > Transition Elements
Pack sizes Available in standard laboratory quantities as per supplier specifications
Physical form Solid, typically in powder or crystalline form
Storage Store in a cool, dry place away from moisture and direct sunlight

This compound should be stored in a cool, dry environment to maintain its stability and effectiveness. It is recommended to use airtight containers to prevent exposure to moisture and air, which can affect its chemical integrity. Due to its relative non-toxicity, standard laboratory safety protocols should be followed, including the use of gloves and proper ventilation when handling. While it is less toxic than some metal catalysts, it is still important to avoid direct contact and inhalation. Proper labeling and storage conditions ensure its safe use and longevity in laboratory settings.

References cited in the TCI brochure

  1. Robin Gueret. Visible-Light-Driven CarboxyLic Amine Protocol (CLAP) for the Synthesis of 2-Substituted Piperazines under Batch and Flow Conditions Organic Letters, 2020. doi:10.1021/acs.orglett.0c01759
  2. Shashikant U. Dighe. A photochemical dehydrogenative strategy for aniline synthesis Nature, 2020. doi:10.1038/s41586-020-2539-7

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