[NH2Me2][(RuCl((S)-binap))2(mu-Cl)3] TCI N1016

Chemical Identity

CAS No.: 199541-17-8
PubChem: CID 91972114·SID 253660974
Formula: C90H72Cl5NP4Ru2
Molecular weight: 1670.8 g/mol

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: dimethylazanium;bis([1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane);bis(ruthenium(2+));pentachloride
SMILES: C[NH2+]C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Ru+2].[Ru+2]
InChIKey: LFCGWRXZQGOBMD-UHFFFAOYSA-J

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TCI N1016 199541-17-8 [NH2Me2][(RuCl((S)-binap))2(mu-Cl)3] is a chiral catalyst used in asymmetric synthesis. This compound plays a critical role in chemical reactions requiring precise control over stereochemistry, particularly in the synthesis of compounds with specific molecular structures. Its unique properties make it an essential tool for researchers aiming to achieve high enantioselectivity in their experiments. The compound is widely utilized in both academic and industrial research settings where the production of chiral molecules is necessary.

The compound’s chiral nature and active site enable it to selectively catalyze reactions, leading to the formation of desired enantiomers with high efficiency. Its complex structure allows for effective interaction with substrates, enhancing reaction rates and reducing byproduct formation. This makes it a preferred choice for applications where stereochemical control is paramount. The material’s stability and reactivity under controlled conditions further contribute to its reliability in laboratory environments.

In Indonesian laboratories, this compound is frequently used in organic chemistry research, especially in asymmetric synthesis and drug development. Researchers in educational and research institutions rely on it for experiments that require precise stereoselective outcomes. Its effectiveness in producing specific molecular configurations has made it a standard in advanced chemical studies across various scientific disciplines.

Advantages (TCI brochure)

Converts ketones to amines via reductive amination in high yields and high enantioselectivity
Converts 1,3-dicarbonyl compounds to alcohols in high yields and high enantioselectivity
High turnover number

TCI brochures (PDF)

Ruthenium Complex Catalysts for Asymmetric Hydrogenation to Optically Active Amines 2025-11-10 · p. 2
Hydrogenation Catalysts 2025-11-10 · p. 7

Related TCI products

Asymmetric synthesis for the production of chiral compounds with specific structural configurations
Organic chemistry reactions requiring precise stereochemical control and high enantioselectivity
Drug development processes aiming to synthesize pharmaceuticals with defined stereochemistry
Research in catalytic processes involving chiral ligands and transition metal complexes
Advanced chemical studies focused on the development of new synthetic methodologies

From the TCI brochure

Asymmetric hydrogenation of a bis(chloromethyl) 1,3-diketone (drawn in brochure) to the chiral 1,3-diol product, MeOH, 110 C

Brand	TCI
CAS number	199541-17-8
Molecular formula	—
Purity	—
Category	Chemistry > Asymmetric Synthesis > Chiral Catalysts, Chiral Ligands, Chiral Reagents
Pack sizes	Available in various quantities as per supplier specifications
Physical form	Solid or powder, depending on the specific formulation
Storage	Store in a cool, dry place away from light and moisture

Data from the TCI brochure

Katalis (loading)	0.2 mol% (H2 (128 bar), MeOH, 110 C)

Source: TCI brochure RR055 (2025-11-10)

This compound should be stored in a cool, dry environment, away from direct light and moisture to maintain its stability and effectiveness. It is recommended to use airtight containers to prevent exposure to air and humidity. Due to its chemical nature, it should be handled with appropriate personal protective equipment, including gloves and safety goggles. The material is not classified as hazardous under standard laboratory conditions, but standard laboratory safety protocols should still be followed. Proper labeling and storage conditions are essential to ensure the integrity of the compound during handling and use.

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