[RuCl(p-cymene)((S)-binap)]Cl TCI R0147

Chemical Identity

CAS No.: 130004-33-0
PubChem: CID 46198548·SID 253662112
Formula: C54H46Cl2P2Ru
Molecular weight: 928.9 g/mol
Purity: >90.0%(HPLC)
Reference databases: ECHA

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: [1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene;ruthenium(2+);dichloride
SMILES: CC1=CC=C(C=C1)C(C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Cl-].[Cl-].[Ru+2]
InChIKey: WNHLGYRPKARUHY-UHFFFAOYSA-L

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Berat 200mg 1g

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TCI R0147 130004-33-0 [RuCl(p-cymene)((S)-binap)]Cl is a chiral metal complex widely used in asymmetric synthesis. This compound functions as a highly effective chiral catalyst, enabling the production of asymmetric compounds with precise stereochemistry. In laboratory settings, it plays a crucial role in accelerating chemical reactions while maintaining the integrity of the molecular structure. Its unique properties make it an essential tool for researchers aiming to achieve high selectivity and yield in complex synthetic processes.

The compound’s chiral structure allows it to direct reactions toward specific products, making it a preferred choice for organic chemists. Its high purity and stability ensure consistent results across multiple experiments. Additionally, its resistance to various chemical conditions makes it versatile for use in different reaction environments. These characteristics contribute to its widespread adoption in both academic and industrial research.

In Indonesian laboratories, this material is commonly used in organic chemistry research, particularly in asymmetric synthesis projects. It supports the development of new compounds with specific stereochemical configurations, which are vital in pharmaceutical and materials science applications. Its reliability and performance make it a go-to choice for researchers seeking precision and efficiency in their work.

Advantages (TCI brochure)

Reduces various olefins and functionalized ketones in high yields and high enantioselectivity
High turnover number

TCI brochures (PDF)

Ruthenium Complex Catalysts for Asymmetric Hydrogenation of Olefins and Functionalized Ketones 2024-12-10 · p. 1
Hydrogenation Catalysts 2025-11-10 · p. 7

Related TCI products

Asymmetric Synthesis: This compound is ideal for asymmetric synthesis due to its ability to direct reactions toward specific stereochemical outcomes, ensuring high enantioselectivity.
Organic Chemistry Research: It supports the development of complex organic molecules with precise stereochemistry, making it essential for advanced chemical studies.
Catalytic Reactions: Its catalytic properties enable efficient and selective reactions, reducing the need for excess reagents and improving reaction yields.
Pharmaceutical Development: The compound is used in the synthesis of chiral pharmaceutical intermediates, contributing to the creation of drugs with specific stereochemical configurations.
Materials Science: It aids in the production of chiral materials with unique properties, expanding the range of applications in advanced chemical research.

From the TCI brochure

Asymmetric hydrogenation of an acetoxymethyl-substituted unsaturated lactone (substrate drawn only) to the corresponding saturated lactone

Brand	TCI
CAS number	130004-33-0
Molecular formula	—
Purity	—
Category	Chemistry > Asymmetric Synthesis > Chiral Catalysts, Chiral Ligands, Chiral Reagents
Pack sizes	Available in various quantities as per supplier specifications
Physical form	Solid or powder, depending on packaging
Storage	Store in a cool, dry place away from moisture and direct sunlight

Data from the TCI brochure

Catalyst loading	1 mol% (H2 (~ 80 atm), MeOH, 25 °C)
Kemasan	200mg / 1g

Source: TCI brochure RR053 (2024-12-10)

This compound should be stored in a cool, dry environment to maintain its stability and effectiveness. It is recommended to use airtight containers to prevent exposure to moisture and air, which can degrade its properties. Due to its chemical nature, it should be handled with care, using appropriate personal protective equipment such as gloves and safety goggles. It is important to keep the material away from incompatible substances to avoid any potential reactions. In laboratory settings, proper ventilation should be maintained when handling this compound to ensure a safe working environment. Regular inspection of storage conditions is advised to ensure the material remains in optimal condition for use.

References cited in the TCI brochure

Erika Soares Bronze-Uhle. Enantioselective hydrogenation of 4-(hydroxymethyl)furan-2(5H)-one derivatives Journal of Molecular Catalysis A: Chemical, 2006. doi:10.1016/j.molcata.2006.05.066