[NH2Me2][(RuCl((R)-dm-segphos(regR)))2(mu-Cl)3] TCI N1023

Chemical Identity

CAS No.: 935449-46-0
PubChem: CID 91972117·SID 253660978
Formula: C94H96Cl5NO8P4Ru2
Molecular weight: 1871.1 g/mol

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: bis([4-[5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl]-1,3-benzodioxol-5-yl]-bis(3,5-dimethylphenyl)phosphane);dimethylazanium;bis(ruthenium(2+));pentachloride
SMILES: CC1=CC(=CC(=C1)P(C2=C(C3=C(C=C2)OCO3)C4=C(C=CC5=C4OCO5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.CC1=CC(=CC(=C1)P(C2=C(C3=C(C=C2)OCO3)C4=C(C=CC5=C4OCO5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.C[NH2+]C.[Cl-].[Cl-].[Cl-].[C
InChIKey: ICOHGSVVYSKYTD-UHFFFAOYSA-J

Rp 1.538.250,00

~~Rp 1.090.950,00~~ Rp 1.538.250,00

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Berat 200mg 1g

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TCI N1023, with the CAS number 935449-46-0, is a complex metal compound based on ruthenium used in catalytic hydrogenation reactions. This material serves as a highly efficient catalyst in various chemical processes, particularly in the field of organic and inorganic chemistry. Its unique structure, involving ruthenium ions and ligands such as (R)-dm-segphos, enables it to facilitate hydrogenation reactions under controlled conditions. In the laboratory, it plays a crucial role in accelerating chemical transformations while maintaining the integrity of the substrate.

The compound is favored for its exceptional catalytic activity and selectivity, making it a preferred choice in both academic and industrial research settings. Its ability to function as a highly specific catalyst allows for precise control over reaction outcomes, which is essential in advanced chemical synthesis. Additionally, the compound exhibits good stability under specific reaction conditions, minimizing degradation and ensuring consistent performance. This reliability contributes to its widespread use in modern laboratory environments.

In Indonesian laboratories, TCI N1023 is commonly used in research related to catalytic hydrogenation, particularly in organic chemistry applications. Its effectiveness in promoting hydrogenation reactions without altering the fundamental structure of the substrate makes it an essential tool for chemists working on complex synthetic pathways. The compound is also valued for its adaptability in various experimental setups, supporting both basic and applied research in the chemical sciences.

Advantages (TCI brochure)

Converts ketones to amines via reductive amination in high yields and high enantioselectivity
Converts 1,3-dicarbonyl compounds to alcohols in high yields and high enantioselectivity
High turnover number

TCI brochures (PDF)

Ruthenium Complex Catalysts for Asymmetric Hydrogenation to Optically Active Amines 2025-11-10 · p. 1
Hydrogenation Catalysts 2025-11-10 · p. 4

Related TCI products

Catalytic Hydrogenation: This item is ideal for hydrogenation reactions due to its high catalytic activity and selectivity, enabling efficient conversion of substrates under controlled conditions.
Organic Synthesis: It supports the development of complex organic molecules by facilitating selective hydrogenation, which is crucial in the synthesis of pharmaceuticals and fine chemicals.
Inorganic Chemistry Research: The compound's unique structure makes it suitable for studying the behavior of ruthenium-based catalysts in inorganic systems.
Green Chemistry Initiatives: Its efficiency and reduced byproduct formation align with sustainable chemical processes, making it a preferred catalyst in eco-friendly research.
Industrial Process Optimization: It is used to enhance the efficiency of industrial hydrogenation processes, contributing to cost-effective and scalable chemical manufacturing.

From the TCI brochure

Asymmetric reductive amination of a ketoester (drawn in brochure) with ammonium salicylate to the optically active beta-amino ester product

Brand	TCI
CAS number	935449-46-0
Molecular formula	—
Purity	—
Category	Chemistry > Catalysis and Inorganic Chemistry > Hydrogenation [Catalysis]
Pack sizes	—
Physical form	—
Storage	Store in a cool, dry place away from moisture and direct light

Data from the TCI brochure

Katalis (loading)	0.13 mol% (H2 (30 bar), ammonium salicylate, EtOH, 90 C)

Source: TCI brochure RR055 (2025-11-10)

This compound should be stored in a cool, dry environment to maintain its stability and catalytic properties. It is recommended to use airtight containers to prevent exposure to moisture and air, which could lead to degradation. Due to its chemical nature, it should be handled with appropriate personal protective equipment, such as gloves and safety goggles, to ensure laboratory safety. Avoid contact with incompatible substances, and always follow standard laboratory safety protocols when working with catalysts. Proper storage and handling are essential to preserve the compound’s effectiveness and ensure safe usage in research settings.

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