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CAS 90076-65-6

Lithium Bis(trifluoromethanesulfonyl)imide TCI B2542

Lithium Bis(trifluoromethanesulfonyl)imide TCI B2542

Chemical Identity

Other names
LiTFSI · Li (CF3SO2)2N
CAS No.
90076-65-6
PubChem
CID 3816071·SID 87557946
Formula
C2F6LiNO4S2
Molecular weight
287.1 g/mol
Purity
>99.0%(T)
Reference databases
ChemSpider·ECHA·Wikipedia
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
lithium bis(trifluoromethylsulfonyl)azanide
SMILES
[Li+].C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
InChIKey
QSZMZKBZAYQGRS-UHFFFAOYSA-N
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Lithium Bis(trifluoromethanesulfonyl)imide (LiBF₄) is an ionic salt widely used in modern chemical applications. It serves as a key building block in the synthesis of fluorinated compounds, particularly in reactions involving trifluorosulfonimide ions. This material is essential in laboratory settings where stability and controlled reactivity are required. Its importance extends to electrochemical applications, where it functions as an electrolyte in batteries and electrochemical cells. Due to its versatility and reliability, LiBF₄ is a staple in both organic and inorganic chemistry research.

The properties that make LiBF₄ a preferred choice include its molecular stability, high ionic conductivity, and resistance to degradation. These characteristics ensure that it remains effective under various experimental conditions. Its high melting point allows for use in high-temperature environments without significant physical changes. Additionally, LiBF₄ exhibits controlled reactivity, making it suitable for a wide range of chemical processes. These attributes make it a reliable and consistent material for laboratory use.

In Indonesian laboratories, LiBF₄ is commonly used in chemical research, especially in academic and research institutions focused on organic and electrochemical studies. It plays a vital role in the development of new materials and compounds, supporting both educational and industrial research efforts. Its availability and performance make it a standard component in many laboratory workflows across Indonesia.

  • Electrochemical research utilizes LiBF₄ as an electrolyte due to its high ionic conductivity and stability in high-temperature environments.
  • Organic synthesis benefits from LiBF₄’s role in fluorinated compound production, supporting reactions that require trifluorosulfonimide ions.
  • Battery development relies on LiBF₄ for its electrochemical properties, making it suitable for advanced energy storage systems.
  • Analytical chemistry employs LiBF₄ in ion mobility spectrometry and other techniques requiring stable ionic compounds.
  • Materials science research uses LiBF₄ to create and test new fluorinated materials with specific chemical and physical properties.

From the TCI brochure

  • Additive for the hole transport layer of perovskite solar cells (comparison baseline for OA-TFSI)

Brand TCI
CAS number 90076-65-6
Molecular formula —
Purity —
Category Chemistry > Building Blocks > Fluorinated Building Blocks
Pack sizes Available in various quantities as per standard laboratory supply
Physical form Solid powder
Storage Store in a cool, dry place away from moisture and direct sunlight

LiBF₄ should be stored in a cool, dry environment to maintain its chemical stability. It is recommended to use airtight containers to prevent moisture absorption, which could affect its performance. Due to its ionic nature, it is important to handle it with care to avoid contamination. Laboratory personnel should wear appropriate personal protective equipment when working with this material. Regular inspection of storage conditions ensures that the material remains suitable for use in chemical experiments. Proper storage and handling are essential to preserve its properties and ensure safe laboratory practices.

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