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TCI

CAS 1092775-62-6

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate TCI B6161

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate TCI B6161

Chemical Identity

Other names
Ir[dF(CF3)ppy]2(bpy)PF6 · (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate
CAS No.
1092775-62-6
PubChem
CID 71534097·SID 468590950
Formula
C34H18F16IrN4P
Molecular weight
1,009.71 g/mol
Purity
>90.0%(HPLC)
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
bis(2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine);iridium(3+);2-pyridin-2-ylpyridine;hexafluorophosphate
SMILES
C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC(=NC=C1C(F)(F)F)C2=C(C=C(C=[C-]2)F)F.C1=CC(=NC=C1C(F)(F)F)C2=C(C=C(C=[C-]2)F)F.F[P-](F)(F)(F)(F)F.[Ir+3]
InChIKey
ZCNUFCYLERNPGN-UHFFFAOYSA-N
MDL
MDL28987331
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TCI B6161 (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate is a cyclometalated iridium(III) complex widely employed as a photoredox catalyst in visible-light-driven organic synthesis. This compound exhibits strong photoluminescent properties, making it a valuable dopant in OLED (Organic Light-Emitting Diode) research and materials science. Its versatility extends to photocatalytic C-C and C-N bond-forming reactions, as well as mechanistic studies in electron transfer and biomimetic systems.

--- *Asumsi: Catatan penyimpanan mengikuti rekomendasi umum penanganan kompleks iridium fotosensitif dari TCI.*

From the TCI brochure

  • Photocatalyst in scheme step (e) with methyl acrylate, CH3OH, acetone, blue light

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References cited in the TCI brochure

  1. Taeho Kang. Multifaceted Substrate–Ligand Interactions Promote the Copper-Catalyzed Hydroboration of Benzylidenecyclobutanes and Related Compounds ACS Catalysis, 2020. doi:10.1021/acscatal.0c03622