2-[(2-Bromo-2-methylpropanoyl)oxy]ethyl Acrylate TCI B6381

Chemical Identity

Other names: 2-(2-Bromoisobutyryloxy)ethyl Acrylate · 2-(Acryloyloxy)ethyl 2-Bromoisobutyrate · 2-(2-Bromo-2-methyl-1-oxopropoxy)ethyl 2-Propenoate
CAS No.: 213453-02-2
PubChem: CID 21216989
Formula: C9H13BrO4
Molecular weight: 265.10 g/mol
Purity: >95.0%(GC)

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: 2-prop-2-enoyloxyethyl 2-bromo-2-methylpropanoate
SMILES: CC(C)(C(=O)OCCOC(=O)C=C)Br
InChIKey: QTJPDGNUTQHUOO-UHFFFAOYSA-N

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TCI B6381, 2-[(2-Bromo-2-methylpropanoyl)oxy]ethyl acrylate (CAS 213453-02-2), is a bifunctional acrylate monomer bearing an α-bromoisobutyrate group. This dual functionality allows it to act simultaneously as a polymerizable monomer and as an ATRP initiating site, making it a practical "inimer" for controlled radical polymerization. Researchers commonly apply it to hyperbranched polymers, star architectures, and bottlebrush copolymers where branch points must be introduced in a controlled manner. Supplied in 1 g and 5 g packs, it should be stored cool, tightly closed, and protected from light to prevent premature polymerization.