TCI C0439 Cyanoacetic Acid (CAS 372-09-8) combines a carboxylic acid group with an alpha nitrile, giving it a highly reactive active methylene centre. It is a standard reagent for Knoevenagel condensations and cyanoacetylation reactions in organic synthesis. The cyanoacrylic acid motif it forms is widely used as an anchoring group in dye-sensitised solar cell research, while the acid itself is a precursor to cyanoacetate esters and nitrogen heterocycles. The hygroscopic and corrosive solid should be stored tightly sealed in a cool, dry place and handled with gloves and eye protection.
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- Bondock et al. (2007). Utility of Cyanoacetic Acid Hydrazide in Heterocyclic Synthesis. ChemInform doi:10.1002/chin.200704233
- IKIZLER et al. (1993). ChemInform Abstract: A Study of Cyanoacetic Acid Hydrazide.. ChemInform doi:10.1002/chin.199306171
- El Kaïm et al. (2015). The Ugi Reaction of Cyanoacetic Acid as a Route to Tetramic Acid Derivatives. Synlett doi:10.1055/s-0035-1560050
References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.
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