Methyl 4-Chloro-2-methylbutyrate TCI C1319

Chemical Identity

Other names: 4-Chloro-2-methylbutyric Acid Methyl Ester
CAS No.: 13888-03-4
PubChem: CID 11263584·SID 87566333
Formula: C6H11ClO2
Molecular weight: 150.60 g/mol
Purity: >98.0%(GC)

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: methyl 4-chloro-2-methylbutanoate
SMILES: CC(CCCl)C(=O)OC
InChIKey: ZDDYJHVTUSUPFC-UHFFFAOYSA-N
MDL: MDL00198001

Rp 1.140.300,00

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Berat 5g 25g

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TCI C1319 Methyl 4-Chloro-2-methylbutyrate is a bifunctional aliphatic ester bearing a terminal alkyl chloride and an alpha methyl branch. The chloride serves as a leaving group for alkylating nucleophiles, while the ester can be hydrolysed, reduced, or cyclised into lactams and lactones. Its alpha methyl group also introduces a stereogenic centre relevant to stereochemical studies. AMI Scientific offers this TCI product in 5 g and 25 g packs; handle it in a fume hood and keep the container tightly closed.

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Ferguson et al. (1997). Mechanism and Stereochemistry of the Reaction of Dichloroplatinum(II) Complexes with Diazo Compounds. X-ray Structures of Four Key Products: [(2R,3R)-Bis(diphenylphosphino)butane]chloro- [(S)-chloro(methoxycarbonyl)methyl]platinum(II), (η4-1,5-Cyclooctadiene)[3-chloro-5-(dimethoxyphosphonyl)-2- methoxy-4,1,2-platinaoxaphospholane P-oxide], (R,R)-[Chloro(dimethoxyphosphonyl)methyl][chloro- (trimethylsilyl)methyl](1,5-cyclooctadiene)platinum(II), and Chloro[chloro(dimethoxyphosphonyl)methyl](η4-1,5-cyclooctadiene)platinum(II). Organometallics doi:10.1021/om9607964

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