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CAS 145022-45-3

1-Ethyl-3-methylimidazolium Methanesulfonate TCI E0755

1-Ethyl-3-methylimidazolium Methanesulfonate TCI E0755
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Description

TCI E0755 1-Ethyl-3-methylimidazolium Methanesulfonate is an ionic liquid built from the EMIM cation paired with a methanesulfonate, or mesylate, anion. This salt belongs to the hydrophilic class of ionic liquids, meaning it mixes readily with water and other polar solvents. In the laboratory it serves as an alternative solvent with extremely low vapour pressure, as a reaction medium for organic transformations, and as a component of biomass dissolution systems. Its presence allows researchers to run reactions at elevated temperatures without losing solvent to evaporation, while also opening the possibility of recovering and recycling the medium.

The property that drives its selection is the combination of a mesylate anion — weakly basic and capable of hydrogen bonding — with a thermally stable imidazolium cation. The methanesulfonate anion is regarded as more benign than halogenated or fluorine-based anions: it generates no fluoride by-products and is comparatively straightforward to handle. This ionic liquid also exhibits ionic conductivity useful for electrochemical work, together with the ability to dissolve polar compounds, inorganic salts, and certain natural polymers that resist dissolution in conventional organic solvents.

In Indonesian laboratories, this material typically appears in university and institutional research groups working on green solvents, organic synthesis methodology, biomass and lignocellulose processing, and electrochemistry. It is generally purchased in small research quantities for method development and screening studies rather than for routine bulk use, and is often evaluated alongside other imidazolium salts to compare anion effects within a given reaction or dissolution system.

Laboratory Applications

  • Green solvent substitution studies — its very low vapour pressure removes the solvent-loss and vapour-emission problems associated with volatile organic solvents in high-temperature work.
  • Reaction medium for organic transformations — the thermally stable imidazolium cation lets synthetic chemists hold reactions at elevated temperature while the medium itself remains intact and recoverable.
  • Biomass and natural polymer dissolution — the hydrogen-bonding mesylate anion helps break up polar natural polymers that conventional organic solvents cannot dissolve effectively.
  • Electrochemical experiments — the intrinsic ionic conductivity of this salt allows it to function as both solvent and electrolyte medium in electrochemical cell studies.
  • Dissolution of polar compounds and inorganic salts — its hydrophilic character and miscibility with water and polar solvents support sample preparation and homogeneous reaction setups.

Specifications

  • Brand: TCI (Tokyo Chemical Industry)
  • CAS number: 145022-45-3
  • Catalogue number: E0755
  • Category: Chemistry > Specialty Synthesis > Ionic Liquids [Specialty Synthesis]
  • Pack sizes: available in standard TCI research-scale packaging; please confirm the currently offered size when ordering
  • Storage: keep in a tightly closed container, protected from moisture

Handling and Storage

Store the container tightly closed in a cool, dry, well-ventilated area away from moisture, since this ionic liquid is hydrophilic and will readily take up water from humid air — a particular concern in Indonesian ambient conditions. Keep it in its original supplier packaging or in a compatible tightly sealed glass container, and reseal promptly after each withdrawal. Handle in a fume hood using gloves, safety glasses, and a laboratory coat, transfer with clean dry glassware or pipettes to avoid contamination, and consult the manufacturer's safety data sheet before first use and before disposal.

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