Collection: Phosphine Ligands [Cross-coupling Reaction using Transition Metal Catalysts]

Phosphine Ligands [Cross-coupling Reaction using Transition Metal Catalysts] — contains phosphine ligands, compounds with a trivalent phosphorus atom that donates an electron pair, in structural variations such as tridentate phosphines, biaryl diphosphines, and phosphines substituted with electron-withdrawing aryl groups. This group regulates the electronic and steric properties of the transition metal center in catalysts for carbon-carbon bond-forming reactions.

Phosphine Ligands are used paired with transition metals such as palladium or nickel in cross-coupling reactions, for example Suzuki, Negishi, and Buchwald-Hartwig, to form carbon-carbon as well as carbon-nitrogen bonds. Synthetic organic chemists and pharmaceutical process developers use biaryl or tridentate framework variations to tune catalyst activity and selectivity on challenging substrates.

Example products in this collection: TCI V0132 384842-25-5 vBRIDP(regR), TCI B5957 325773-62-4 2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1'-biphenyl, TCI T4304 22031-12-5 1,1,1-Tris(diphenylphosphinomethyl)ethane, TCI B6783 23582-02-7 Bis(2-diphenylphosphinoethyl)phenylphosphine, TCI T4121 3411-48-1 Tri(naphthalen-1-yl)phosphane, TCI B6930 1055888-89-5 3-(Di-tert-butylphosphaneyl)propane-1-sulfonic Acid, TCI T4115 13406-29-6 Tris[4-(trifluoromethyl)phenyl]phosphine, TCI C2981 384842-24-4 Cy-vBRIDP(regR).

Selection takes into account the coordination geometry (bidentate or tridentate), the electronic properties of substituents on the aryl rings, and sensitivity to oxidation that may require handling under an inert atmosphere. All products are original products of Tokyo Chemical Industry (TCI) Japan, with purity, packaging, and storage conditions listed on each item's page.

Other parallel categories under Cross-coupling Reaction using Transition Metal Catalysts [C-C Bond Formation], often used together in a single laboratory workflow:

• Palladium Catalysts [Cross-coupling Reaction using Transition Metal Catalysts]
• N-Heterocyclic Carbene (NHC) Ligands [Cross-coupling Reaction using Transition Metal Catalysts]
• Nickel [Catalysis and Inorganic Chemistry]
• Nickel Catalysts [Cross-coupling Reaction using Transition Metal Catalysts]
• Copper Catalysts [Cross-coupling Reaction using Transition Metal Catalysts]
• Bases and Additives [Cross-coupling Reaction using Transition Metal Catalysts]

Back to Cross-coupling Reaction using Transition Metal Catalysts [C-C Bond Formation]. For large-volume procurement, special packaging, or specific grades, contact the AMI Scientific team, the official distributor of TCI Japan in Indonesia, to check availability and lead time directly from Japan.