(R)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogenphosphate TCI B6250

Chemical Identity

Other names: (R)-TRIP · (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-Oxide
CAS No.: 791616-63-2
PubChem: CID 11498681·SID 468590999
Formula: C50H57O4P
Molecular weight: 752.98 g/mol
Purity: >98.0%(HPLC)

Full identifiers (IUPAC, SMILES, InChIKey)

IUPAC: 13-hydroxy-10,16-bis[2,4,6-tri(propan-2-yl)phenyl]-12,14-dioxa-13lambda5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
SMILES: CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC3=CC=CC=C3C4=C2OP(=O)(OC5=C4C6=CC=CC=C6C=C5C7=C(C=C(C=C7C(C)C)C(C)C)C(C)C)O)C(C)C
InChIKey: AGQAQYPGJDBIQR-UHFFFAOYSA-N
MDL: MDL10567009

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Berat 250mg 1g

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(R)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogenphosphate is a chiral phosphoric acid organocatalyst highly valued for asymmetric synthesis applications. It serves as a powerful catalyst in enantioselective transformations including Mannich reactions, asymmetric Friedel-Crafts reactions, and transfer hydrogenations. The bulky 2,4,6-triisopropylphenyl substituents provide a highly rigid chiral environment around the BINOL backbone, delivering excellent stereocontrol and high yields in laboratory-scale reactions.