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TCI

CAS 874948-63-7

(S)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate TCI B6259

(S)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate TCI B6259

Chemical Identity

Other names
(S)-TRIP · (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-Oxide
CAS No.
874948-63-7
PubChem
CID 11498681·SID 468591005
Formula
C50H57O4P
Molecular weight
752.98 g/mol
Purity
>98.0%(HPLC)
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
13-hydroxy-10,16-bis[2,4,6-tri(propan-2-yl)phenyl]-12,14-dioxa-13lambda5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
SMILES
CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC3=CC=CC=C3C4=C2OP(=O)(OC5=C4C6=CC=CC=C6C=C5C7=C(C=C(C=C7C(C)C)C(C)C)C(C)C)O)C(C)C
InChIKey
AGQAQYPGJDBIQR-UHFFFAOYSA-N
MDL
MDL10567009
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(S)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate is a chiral BINOL-derived phosphoric acid featuring TRIP substituents, widely utilized as a chiral Brønsted acid catalyst in asymmetric organocatalysis. This compound facilitates a range of stereoselective transformations including Mannich-type reactions, Friedel–Crafts alkylations, and cycloadditions with excellent enantioselectivity. It is an essential building block for academic and industrial research laboratories focusing on asymmetric synthesis and pharmaceutical intermediate development.

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