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TCI

CAS 100-64-1

Cyclohexanone Oxime TCI C0490

Cyclohexanone Oxime TCI C0490

Chemical Identity

CAS No.
100-64-1
Formula
C6H11NO
Molecular weight
113.16 g/mol
Purity
>98.0%(GC)
Full identifiers (IUPAC, SMILES, InChIKey)
IUPAC
N-cyclohexylidenehydroxylamine
SMILES
C1CCC(=NO)CC1
InChIKey
VEZUQRBDRNJBJY-UHFFFAOYSA-N
MDL
MDL00001660
PubChem
CID 7517
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TCI C0490 Cyclohexanone Oxime (CAS 100-64-1) is the oxime derivative of cyclohexanone and a classic intermediate for the Beckmann rearrangement. It is widely used to demonstrate the conversion of an oxime into a lactam, as well as hydrolysis back to the parent ketone and reduction to the corresponding amine. Its crystalline form also makes it a convenient substrate for recrystallisation practice. AMI Scientific offers this TCI building block in both small and large packs for teaching and synthetic research.

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  • Du et al. (2017). Organocatalyzed Beckmann rearrangement of cyclohexanone oxime in a microreactor: Kinetic model and product inhibition. AIChE Journal doi:10.1002/aic.15946
  • FAN et al. (1999). Synthesis of Cyclohexanone Oxime from Cyclohexanone and Ammonia.. Journal of The Japan Petroleum Institute doi:10.1627/jpi1958.42.201
  • Zajacek et al. (1997). Cyclohexanone oxime production. Zeolites doi:10.1016/s0144-2449(97)85023-3

References were compiled automatically from Crossref and every DOI was verified to exist. AMI Scientific is not affiliated with the authors or the publishers.