TCI C0624 2'-Chloroacetoacetanilide (CAS 93-70-9) is a non-heterocyclic building block from the acetoacetanilide family, bearing a chlorine substituent at the ortho position of the anilide ring. Its active methylene group makes it a classic coupling component for diazonium salts, which is why it appears frequently in azo dye and pigment research. The same β-ketoamide framework can also be cyclised toward heterocyclic scaffolds in multistep organic synthesis. AMI Scientific supplies this TCI reagent in 25 g and 500 g packs, allowing both exploratory reactions and repeated preparative work.
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- Arjunan et al. (2013). Vibrational, NMR and quantum chemical investigations of acetoacetanilde, 2-chloroacetoacetanilide and 2-methylacetoacetanilide. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy doi:10.1016/j.saa.2013.06.003
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